Progress in the chemistry of molecular actinide-nitride compounds
M Keener, L Maria, M Mazzanti - Chemical Science, 2023 - pubs.rsc.org
The chemistry of actinide-nitrides has witnessed significant advances in the last ten years
with a large focus on uranium and a few breakthroughs with thorium. Following the early …
with a large focus on uranium and a few breakthroughs with thorium. Following the early …
Multimetallic uranium nitride cubane clusters from dinitrogen cleavage
Dinitrogen cleavage provides an attractive but poorly studied route to the assembly of
multimetallic nitride clusters. Here, we show that the monoelectron reduction of the …
multimetallic nitride clusters. Here, we show that the monoelectron reduction of the …
Temperature induced single-crystal to single-crystal transformation of uranium azide complexes
K Li, T Rajeshkumar, Y Zhao, T Wang… - Chemical …, 2024 - pubs.rsc.org
The monomeric and dimeric uranium azide complexes {[(CH3) 2NCH2CH2NPiPr2] 2U (N3)
2}(2) and {[(CH3) 2NCH2CH2NPiPr2] 2U (N3) 2} 2 (3) were synthesized by treating complex …
2}(2) and {[(CH3) 2NCH2CH2NPiPr2] 2U (N3) 2} 2 (3) were synthesized by treating complex …
Photolysis, Thermolysis, and Reduction of a Uranium Azide Complex Supported by a Double-Layer N–P Ligand
P Wang, Y Zhao, C Zhu - Organometallics, 2022 - ACS Publications
A double-layer N–P ligand-supported uranium azide complex 2 ([N (CH2CH2NP i Pr2)
3UN3] 2) was synthesized by the reaction of a uranium precursor [N (CH2CH2NP i Pr2) …
3UN3] 2) was synthesized by the reaction of a uranium precursor [N (CH2CH2NP i Pr2) …
Reactivity of a triamidoamine terminal uranium (VI)-nitride with 3d-transition metal metallocenes
J Seed, PA Cleaves, GR Hatton, DM King… - Chemical …, 2024 - pubs.rsc.org
Reactions between [(TrenTIPS) UVI N](1, TrenTIPS={N (CH2CH2NSiPri3) 3} 3) and [MII
( 5-C5R5) 2](M/R= Cr/H, Mn/H, Fe/H, Ni/H) were intractable, but M/R= Co/H or Co/Me …
( 5-C5R5) 2](M/R= Cr/H, Mn/H, Fe/H, Ni/H) were intractable, but M/R= Co/H or Co/Me …
Multiconfigurational actinide nitrides assisted by double Möbius aromaticity
X Lin, X Lu, S Tang, W Wu, Y Mo - Chemical Science, 2024 - pubs.rsc.org
Understanding the bonding nature between actinides and main-group elements remains a
key challenge in actinide chemistry due to the involvement of f orbitals. Herein, we propose …
key challenge in actinide chemistry due to the involvement of f orbitals. Herein, we propose …
Synthesis, structure and redox properties of single-atom bridged diuranium complexes supported by aryloxides
Single-atom (group 15 and group 16 anions) bridged dimetallic complexes of low oxidation
state uranium provide a convenient route to implement multielectron transfer and promote …
state uranium provide a convenient route to implement multielectron transfer and promote …