Tandem transformations and multicomponent reactions utilizing alcohols following dehydrogenation strategy

B Paul, M Maji, K Chakrabarti, S Kundu - Organic & Biomolecular …, 2020 - pubs.rsc.org
The construction of new C–C, C–N and C–O bonds by replacing hazardous and waste
generating chemicals with alcohols as the greener and sustainable reagents is one of the …

Synthetic protocols for aromatic nitration: A review

SS Patel, DB Patel, HD Patel - ChemistrySelect, 2021 - Wiley Online Library
Nitration of aromatic compounds represents a powerful and widely used transformation that
allows introducing nitro group into aromatic systems. New synthetic strategies for aromatic …

Characterization and Reactivity of Copper (II) and Copper (III) σ-Aryl Intermediates in Aminoquinoline-Directed C–H Functionalization

IM Blythe, J Xu, JS Fernandez Odell… - Journal of the …, 2023 - ACS Publications
Over the past decade, numerous reports have focused on the development and applications
of Cu-mediated C–H functionalization reactions; however, to date, little is known about the …

Catalytic ipso‐Nitration of Organosilanes Enabled by Electrophilic N‐Nitrosaccharin Reagent

I Mosiagin, AJ Fernandes, A Budinská… - Angewandte …, 2023 - Wiley Online Library
Nitroaromatic compounds represent one of the essential classes of molecules that are
widely used as feedstock for the synthesis of intermediates, the preparation of nitro‐derived …

Additive-Controlled Divergent Synthesis of Tetrasubstituted 1,3-Enynes and Alkynylated 3H-Pyrrolo[1,2-a]indol-3-ones via Rhodium Catalysis

F Zhao, X Gong, Y Lu, J Qiao, X Jia, H Ni, X Wu… - Organic …, 2021 - ACS Publications
Herein, we report the additive-controlled divergent synthesis of tetrasubstituted 1, 3-enynes
and alkynylated 3 H-pyrrolo [1, 2-a] indol-3-ones through rhodium-catalyzed C–H …

Facile access to nitroarenes and nitroheteroarenes using N-nitrosaccharin

R Calvo, K Zhang, A Passera, D Katayev - Nature communications, 2019 - nature.com
Nitroaromatics and nitroheteroaromatics serve as key building blocks and intermediates in
synthesis, and form the core scaffold of a vast number of materials, dyes, explosives …

Organic nitrating reagents

S Patra, I Mosiagin, R Giri, D Katayev - Synthesis, 2022 - thieme-connect.com
Nitro compounds are vital raw chemicals that are widely used in academic laboratories and
industries for the preparation of various drugs, agrochemicals, and materials. Thus, nitrating …

Chemo-, Regio-, and Stereoselective Assembly of Polysubstituted Furan-2(5H)-ones Enabled by Rh(III)-Catalyzed Domino C–H Alkenylation/Directing Group …

F Zhao, Z Zhou, Y Lu, J Qiao, X Zhang, X Gong… - ACS …, 2021 - ACS Publications
Exploring multistep cascade reactions triggered by C–H activation are recognized as
appealing, yet challenging. Herein, we disclose a Rh (III)-catalyzed domino C–H coupling of …

Electron‐Driven Nitration of Unsaturated Hydrocarbons

S Patra, I Mosiagin, R Giri, T Nauser… - Angewandte Chemie …, 2023 - Wiley Online Library
Herein, we introduce an electrochemically assisted generation of nitryl radicals from ferric
nitrate under mild reaction conditions using a simple setup with inexpensive graphite and …

From N–H Nitration to Controllable Aromatic Mononitration and Dinitration─The Discovery of a Versatile and Powerful N-Nitropyrazole Nitrating Reagent

T Yang, X Li, S Deng, X Qi, H Cong, HG Cheng, L Shi… - JACS Au, 2022 - ACS Publications
Nitroaromatics are tremendously valuable organic compounds with a long history of being
used as pharmaceuticals, agrochemicals, and explosives as well as vital intermediates to a …