Creation from Confusion and Fusion in the Porphyrin World─ The Last Three Decades of N-Confused Porphyrinoid Chemistry

M Toganoh, H Furuta - Chemical Reviews, 2022 - ACS Publications
Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Blooming of confused porphyrinoids—fusion, expansion, contraction, and more confusion

M Toganoh, H Furuta - Chemical Communications, 2012 - pubs.rsc.org
This article introduces an overview of progressively developing chemistry of N-confused
porphyrin and related macrocycles. Study on confusion results in discovery of fusion and …

Core modified porphyrins–a macrocyclic platform for organometallic chemistry

PJ Chmielewski, L Latos-Grażyński - Coordination chemistry reviews, 2005 - Elsevier
An alteration of a metalloporphyrin coordination core, exemplified by 21-heteroporphyrins
and 2-aza-21-carbaporphyrin (N-confused porphyrin, inverted porphyrin), provides a route …

Core chemistry and skeletal rearrangements of porphyrinoids and metalloporphyrinoids

B Szyszko, L Latos-Grażyński - Chemical Society Reviews, 2015 - pubs.rsc.org
Core alteration, affording heteroporphyrinoids and carbaporphyrinoids, allows for the
exploration of porphyrin-like or porphyrin-unlike coordination chemistry. Such a strategy has …

Developments in the metal chemistry of N-confused porphyrin

JD Harvey, CJ Ziegler - Coordination chemistry reviews, 2003 - Elsevier
Since its discovery as a side product in acid catalyzed condensations in 1994, the metal
chemistry of N-confused porphyrins has grown exponentially. Due to the location of an …

Complexes of N‐Confused Porphyrin Derivatives as Ortho‐Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality

S Koniarz, K Szydełko, MJ Białek, K Hurej… - Advanced …, 2024 - Wiley Online Library
A family of transition metal complexes of meso‐aryl‐2‐aza‐21‐carbaporphyrin (N‐confused
porphyrin, NCP) derivatives acting as ortho‐metallating ligands for ruthenium (II), rhodium …

Organometallic chemistry of azuliporphyrins: Synthesis, spectroscopy, electrochemistry, and structural characterization of nickel (II), palladium (II), and platinum (II) …

TD Lash, DA Colby, SR Graham, GM Ferrence… - Inorganic …, 2003 - ACS Publications
Four azuliporphyrins, two meso-unsubstituted and two meso-tetraaryl substituted, were
investigated in the synthesis of novel organometallic compounds. The meso-unsubstituted …

A Janus carbaporphyrin pseudo-dimer

H He, J Lee, Z Zong, J Kim, VM Lynch, J Oh… - Nature …, 2024 - nature.com
Carbaporphyrin dimers, investigated for their distinctive electronic structures and
exceptional properties, have predominantly consisted of systems containing identical …

Conformational Flexibility of 1, 4-Naphthiporphyrin Promotes a Palladium-Mediated Contraction of Naphthalene to Isoindene

B Szyszko, L Latos-Grażyński - Organometallics, 2011 - ACS Publications
The carbaporphyrinoids 5, 10, 15, 20-tetraphenyl-1, 4-naphthiporphyrin and 5, 20-diphenyl-
10, 15-ditolyl-24-thia-1, 4-naphthiporphyrin, which contain a naphthalene ring embedded in …

Oxidation and oxygenation of iron complexes of 2-aza-21-carbaporphyrin

K Rachlewicz, SL Wang, JL Ko, CH Hung… - Journal of the …, 2004 - ACS Publications
Oxidation and oxygenation of (H CTPP H) FeIIBr an iron (II) complex of 2-aza-5, 10, 15, 20-
tetraphenyl-21-carbaporphyrin (CTPP H) H2 have been followed by 1H and 2H NMR …