Metal–ligand cooperation (MLC) has become an important concept in catalysis by transition
metal complexes both in synthetic and biological systems. MLC implies that both the metal …

Abstract Die Metall‐Ligand‐Kooperation (MLC) hat sich zu einem wichtigen Konzept in der
Übergangsmetallkatalyse in synthetischen und biologischen Systemen entwickelt. MLC …

The development of unconventional strategies for the activation of ammonia (NH3) and
water (H2O) is of capital importance for the advancement of sustainable chemical strategies …

Parent amido complexes are crucial intermediates in ammonia-based transformations. We
report a well-defined ferric ammine system [Cp* Fe (1, 2-Ph2PC6H4NH)(NH3)]+([1-NH3]+) …

The synthesis of a phosphorus (III) compound bearing a N, N‐bis (3, 5‐di‐tert‐butyl‐2‐
phenoxy) amide ligand is reported. This species has been found to react with ammonia and …

A geometrically constrained phosphine bearing a tridentate NNS pincer ligand is reported.
The effect of the geometric constraint on the electronic structure was probed by theoretical …

N–N bond cleavage of hydrazines on transition metals is of considerable importance in
understanding the mechanism of biological nitrogen fixation under ambient conditions. We …

A carbene-stabilized dithiolene zwitterion (3) activates ammonia, affording 4• and 5, through
both single-electron transfer (SET) and hydrogen atom transfer (HAT). Reaction products …

A general mechanism for H2 activation by Lewis acid–transition metal (LA-TM) bifunctional
catalysts has been presented via density functional theory (DFT) studies on a representative …

A diazadiphosphapentalene derivative 5 featuring a bent geometry with two phosphorus
atoms at the bridgehead has been synthesized. Under mild conditions, compound 5 readily …