Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces

S Dutta, AJ Gellman - Chemical Society Reviews, 2017 - pubs.rsc.org
Research on surface chirality is motivated by the need to develop functional chiral surfaces
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …

Adsorption and self-assembly of bio-organic molecules at model surfaces: A route towards increased complexity

D Costa, CM Pradier, F Tielens, L Savio - Surface Science Reports, 2015 - Elsevier
Understanding the bio-physical–chemical interactions at nanostructured biointerfaces and
the assembly mechanisms of so-called hybrid nano-composites is nowadays a key issue for …

Adsorption-induced auto-amplification of enantiomeric excess on an achiral surface

Y Yun, AJ Gellman - Nature chemistry, 2015 - nature.com
The homochirality of biomolecules is a signature of life on Earth and has significant
implications in, for example, the production of pharmaceutical compounds. It has been …

Self-assembled monolayers of aromatic thiols stabilized by parallel-displaced π− π stacking interactions

RF Dou, XC Ma, L Xi, HL Yip, KY Wong, WM Lau… - Langmuir, 2006 - ACS Publications
Parallel-displaced π− π stacking interactions have been known to be the dominant force in
stabilizing the double helical structure of DNA and the tertiary structure of proteins. However …

Structures of glycine, enantiopure alanine, and racemic alanine adlayers on Cu (110) and Cu (100) surfaces

RB Rankin, DS Sholl - The Journal of Physical Chemistry B, 2005 - ACS Publications
We have determined the structures of dense adlayers of glycine and alanine on the Cu (110)
and Cu (100) surfaces using plane wave density functional theory. These calculations …

Local structure determination of a chiral adsorbate: Alanine on Cu (1 1 0)

DI Sayago, M Polcik, G Nisbet, CLA Lamont… - Surface science, 2005 - Elsevier
N 1s and O 1s scanned-energy mode photoelectron diffraction (PhD) has been used to
investigate the local structure of a single enantiomer of deprotonated alanine, alaninate …

Probing Conformers and Adsorption Footprints at the Single-Molecule Level in a Highly Organized Amino Acid Assembly of (S)-Proline on Cu(110)

M Forster, MS Dyer, M Persson… - Journal of the American …, 2009 - ACS Publications
Establishing the nanoscale details of organized amino acid assemblies at surfaces is a
major challenge in the field of organic− inorganic interfaces. Here, we show that the dense …

Characterisation of the Interaction of Glycine with Cu (1 0 0) and Cu (1 1 1)

V Efstathiou, DP Woodruff - Surface science, 2003 - Elsevier
Reflection–absorption infrared spectroscopy (RAIRS) has been used to characterise the
interaction of standard and fully deuterated glycine with Cu (100) and Cu (111). RAIRS …

2D random organization of racemic amino acid monolayers driven by nanoscale adsorption footprints: proline on Cu (110)

M Forster, MS Dyer, M Persson, R Raval - … Chemie International Edition, 2010 - infona.pl
Amino acids find their feet: Scanning tunneling microscopy of racemic (R, S)‐proline on Cu
(110) reveals rows of random chiral amino acid sequences, showing that organization is not …

Self-assembly of L-tryptophan on Cu (111) studied by low-temperature scanning tunneling microscopy

Q Xue, Y Zhang, R Li, C Li, N Li, C Yuan, S Hou… - Chinese Chemical …, 2019 - Elsevier
The self-assembly of l-tryptophan on Cu (111) is investigated by an ultrahigh vacuum
scanning tunneling microscope (STM) at 4.4 K. When deposited onto the substrate at around …