Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

Conspectus The combination of two or more unsaturated structural units to form cyclic
organic compounds is commonly referred to as cycloaddition, and the combination of two …

Azomethine imines are considered 1, 3-dipoles of the aza-allyl type which are transient
intermediates and should be generated in situ but can also be stable and isolable …

Arene dearomatization is a straightforward method for converting an aromatic feedstock into
functionalized carbocycles. Enantioselective dearomatizations of chemically inert arenes …

Air-stable azomethine ylides with an unusual pattern of charge distribution were efficiently
prepared via the rhodium-catalyzed reaction between pyridines and 1-sulfonyl-1, 2, 3 …

The development of general catalytic methods for the regio-and stereoselective construction
of chiral N-heterocycles in a diversity-oriented fashion remains a formidable challenge in …

The first phosphine-catalyzed highly enantioselective [3+ 3] cycloaddition of Morita–Baylis–
Hillman carbonates with C, N-cyclic azomethine imines is described. Using a spirocyclic …

Reported herein is the unprecedented gold‐catalyzed formal [4+ 1]/[4+ 3] cycloadditions of
diazo esters with hexahydro‐1, 3, 4‐triazines, thus providing five‐and seven‐membered …

We report asymmetric dearomatization of phenols using Ag carbenoids from α-
diazoacetamides. The Ag catalyst promoted intramolecular dearomatization of phenols …

Amongst nitrogen heterocycles of different ring sizes and oxidation statuses,
dihydropyridines (DHP) occupy a prominent role due to their synthetic versatility and …