Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Degradable and recyclable polymers by reversible deactivation radical polymerization

MR Martinez, K Matyjaszewski - CCS Chemistry, 2022 - chinesechemsoc.org
Reversible deactivation radical polymerization (RDRP) provides unprecedented control over
polymer composition, size, functionality, and topology. Various materials, such as linear …

Light-accelerated depolymerization catalyzed by Eosin Y

V Bellotti, K Parkatzidis, HS Wang… - Polymer …, 2023 - pubs.rsc.org
Retrieving the starting monomers from polymers synthesized by reversible deactivation
radical polymerization has recently emerged as an efficient way to increase the recyclability …

Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …

Photons and photocatalysts as limiting reagents for PET-RAFT photopolymerization

B Parnitzke, T Nwoko, KGE Bradford… - Chemical Engineering …, 2023 - Elsevier
The kinetics of photoinduced electron/energy transfer-reversible addition fragmentation
chain transfer (PET-RAFT) polymerization were investigated using a model system of methyl …

Xanthate-supported photo-iniferter (XPI)-RAFT polymerization: facile and rapid access to complex macromolecules

AC Lehnen, J Gurke, AM Bapolisi, M Reifarth… - Chemical …, 2023 - pubs.rsc.org
Xanthate-supported photo-iniferter (XPI)-reversible addition–fragmentation chain-transfer
(RAFT) polymerization is introduced as a fast and versatile photo-polymerization strategy …

Controlling primary chain dispersity in network polymers: elucidating the effect of dispersity on degradation

T Shimizu, R Whitfield, GR Jones, IO Raji… - Chemical …, 2023 - pubs.rsc.org
Although dispersity has been demonstrated to be instrumental in determining many polymer
properties, current synthetic strategies predominantly focus on tailoring the dispersity of …

Spontaneous Gradients by ATRP and RAFT: Interchangeable Polymerization Methods?

KGE Bradford, RD Gilbert, MASN Weerasinghe… - …, 2023 - ACS Publications
The spontaneous gradient polymerization was investigated by ATRP and RAFT. The model
monomers for both systems were methyl methacrylate (MMA) and ethyl acrylate (EA) …

Plenty of Space in the Backbone: Radical Ring‐Opening Polymerization

F Sbordone, H Frisch - Chemistry–A European Journal, 2024 - Wiley Online Library
Radical polymerization is the most widely applied technique in both industry and
fundamental science. However, its major drawback is that it typically yields polymers with …

[HTML][HTML] Controlling photodegradation in vinyl ketone polymers

MASN Weerasinghe, PA McBeth, MC Mancini… - Chemical Engineering …, 2024 - Elsevier
Polymer degradation has many important applications, ranging from waste management
and reuse of polymers, to targeted delivery in nanomedicine. Vinyl ketone (VK) polymers …