Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Cross-dehydrogenative coupling: a sustainable reaction for C–C bond formations

T Tian, Z Li, CJ Li - Green Chemistry, 2021 - pubs.rsc.org
We are entering an era that emphasizes greenness and sustainability. Based on such a
philosophy, it is critical to uncover novel and original sustainable reaction modes for future …

Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond

X Liu, C Xu, M Wang, Q Liu - Chemical reviews, 2015 - ACS Publications
Method B 692 3.7. Selective Trifluoromethylation of Multi-Functional Substrates 693 3.8.
Enantioselective Trifluoromethylation 695 3.8. 1. Aldehydes and Ketones: With Cinchona …

Catalytic dehydrogenative cross-coupling: forming carbon− carbon bonds by oxidizing two carbon− hydrogen bonds

CS Yeung, VM Dong - Chemical reviews, 2011 - ACS Publications
Inspired by the need for green and sustainable chemistry,(1) synthetic chemists seek more
efficient ways to construct carbon− carbon (C− C) bonds, the essential link in all organic …

sp 2 C–H bond activation in water and catalytic cross-coupling reactions

B Li, PH Dixneuf - Chemical Society Reviews, 2013 - pubs.rsc.org
The metal-catalysed successive activation and functionalisation of sp2 C–H bonds is the at
heart of synthetic innovations for the development of C–C bond cross-coupling processes …

Transition-metal mediated carbon–sulfur bond activation and transformations

L Wang, W He, Z Yu - Chemical Society Reviews, 2013 - pubs.rsc.org
C–S bond activation, cleavage and transformations by means of transition metal compounds
have recently become more and more important in the petroleum industry and synthetic …

Palladium(II)-Catalyzed Direct Carboxylation of Alkenyl C–H Bonds with CO2

K Sasano, J Takaya, N Iwasawa - Journal of the American …, 2013 - ACS Publications
Pd-catalyzed direct carboxylation of alkenyl C–H bonds with carbon dioxide was realized for
the first time. Treatment of 2-hydroxystyrenes and a catalytic amount of Pd (OAc) 2 with …

Transition metal-catalyzed C vinyl–C vinyl bond formation via double C vinyl–H bond activation

X Shang, ZQ Liu - Chemical Society Reviews, 2013 - pubs.rsc.org
Transition metal-catalyzed oxidative dehydrogenative coupling reactions of Caryl–H bonds
with Cvinyl–H bonds to generate a Caryl–Cvinyl bonds have been well developed in recent …

The domino chromone annulation and a transient halogenation-mediated C–H alkenylation toward 3-vinyl chromones

L Fu, Z Xu, JP Wan, Y Liu - Organic Letters, 2020 - ACS Publications
Reported in this paper is a step economical method toward the general synthesis of 3-vinyl
chromones via the reactions between readily available o-hydroxyphenyl enaminones and …

Recent advances in transition-metal-catalyzed C–S activation: from thioester to (Hetero) aryl thioether

F Pan, ZJ Shi - ACS Catalysis, 2014 - ACS Publications
Carbon–sulfur bonds widely exist in natural products, pesticides, and drugs, and their
activation, cleavage, and transformation via transition metal catalysis have become more …