The chemistry of bioluminescence: an analysis of chemical functionalities

I Navizet, YJ Liu, N Ferré, D Roca‐Sanjuán… - …, 2011 - Wiley Online Library
Firefly luciferase is one of the most studied bioluminescent systems, both theoretically and
experimentally. Herein we review the current understanding of the bioluminescent process …

A dual‐color far‐red to near‐infrared firefly luciferin analogue designed for multiparametric bioluminescence imaging

AP Jathoul, H Grounds, JC Anderson… - Angewandte Chemie …, 2014 - Wiley Online Library
Red‐shifted bioluminescent emitters allow improved in vivo tissue penetration and signal
quantification, and have led to the development of beetle luciferin analogues that elicit red …

Local delivery of MoS2/FeS2 heterojunction by biomolecular microneedles for multimodal therapy of infected wounds

W You, Z Cai, F Xiao, J Zhao, X Yu, W Wang… - Chemical Engineering …, 2024 - Elsevier
Infected wound healing is obstructed by not only bacterial infection, but also the formation of
bacterial biofilm. Over the past decades, researchers have developed a large number of …

Spectroscopy of nitrophenolates in vacuo: effect of spacer, configuration, and microsolvation on the charge-transfer excitation energy

SB Nielsen, MB Nielsen, A Rubio - Accounts of Chemical …, 2014 - ACS Publications
Conspectus In a charge-transfer (CT) transition, electron density moves from one end of the
molecule (donor) to the other end (acceptor). This type of transition is of paramount …

Density functional theory calculation of the absorption properties of brown carbon chromophores generated by catechol heterogeneous ozonolysis

ACO Magalhaes, JCG Esteves da Silva… - ACS Earth and Space …, 2017 - ACS Publications
The effect of light-absorbing atmospheric particles on climate change has been incorporated
into climate models, but the absence of brown carbon (BrC) in these models has been …

Rational Improvement of Molar Absorptivity Guided by Oscillator Strength: A Case Study with Furoindolizine‐Based Core Skeleton

Y Lee, A Jo, SB Park - Angewandte Chemie International …, 2015 - Wiley Online Library
The rational improvement of photophysical properties can be highly valuable for the
discovery of novel organic fluorophores. Using our new design strategy guided by the …

Chemiexcitation induced proton transfer: enolate oxyluciferin as the firefly bioluminophore

L Pinto da Silva… - The Journal of Physical …, 2015 - ACS Publications
Firefly bioluminescence is a phenomenon that attracts attention from the research
community because of complex challenges for fundamental investigation, as well as diverse …

Comparison of the photoprotolytic processes of three 7-hydroxycoumarins

R Simkovitch, L Pinto da Silva… - The Journal of …, 2016 - ACS Publications
Steady-state and time-resolved fluorescence techniques, in addition to quantum mechanical
calculations, were employed to study the excited-state proton transfer (ESPT) to solvent of …

Electrostatic catalysis induced by luciferases in the decomposition of the firefly dioxetanone and its analogue

JG Zhou, S Yang, ZY Deng - The Journal of Physical Chemistry B, 2017 - ACS Publications
The variations of the barrier heights in the decomposition of the firefly dioxetanone and its
analogues with the electrostatic field produced by the active site amino acid residues in the …

Theoretical modulation of the color of light emitted by firefly oxyluciferin

LPD Silva, JCGE Da Silva - Journal of Computational Chemistry, 2011 - Wiley Online Library
One of the major mysteries regarding firefly bioluminescence is its pH‐dependent multicolor
variation. At basic pH, the emission is on the yellow–green region, whereas at acid pH, the …