Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Polymer nanosieve membranes for CO2-capture applications

N Du, HB Park, GP Robertson, MM Dal-Cin, T Visser… - Nature materials, 2011 - nature.com
Microporous organic polymers (MOPs) are of potential significance for gas storage,,, gas
separation and low-dielectric applications. Among many approaches for obtaining such …

Kinetics of atom transfer radical polymerization

P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …

Nanostructured functional materials prepared by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Nature chemistry, 2009 - nature.com
Atom transfer radical polymerization (ATRP) is the most extensively studied controlled/living
radical polymerization (CRP) method, with the interest originating primarily in its simplicity …

Marrying click chemistry with polymerization: expanding the scope of polymeric materials

PL Golas, K Matyjaszewski - Chemical Society Reviews, 2010 - pubs.rsc.org
Click chemistry constitutes a class of reactions broadly characterized by efficiency,
selectivity, and tolerance to a variety of solvents and functional groups. By far the most …

'Click'chemistry in polymer and materials science

WH Binder, R Sachsenhofer - Macromolecular Rapid …, 2007 - Wiley Online Library
The modification of polymers after the successful achievement of a polymerization process
represents an important task in macromolecular science. Cycloaddition reactions, among …

1, 3‐Dipolar cycloadditions of azides and alkynes: a universal ligation tool in polymer and materials science

JF Lutz - Angewandte Chemie International Edition, 2007 - Wiley Online Library
In 2001, Sharpless and co‐workers introduced “click” chemistry, a new approach in organic
synthesis that involves a handful of almost perfect chemical reactions. Among these carefully …

The convergence of synthetic organic and polymer chemistries

CJ Hawker, KL Wooley - Science, 2005 - science.org
Several recent conceptual advances, which take advantage of the design criteria and
practical techniques of molecular-level control in organic chemistry, allow preparation of well …

'Click'chemistry in polymer and material science: an update

WH Binder, R Sachsenhofer - Macromolecular Rapid …, 2008 - Wiley Online Library
The metal catalyzed azide/alkyne 'click'reaction (a variation of the Huisgen 1, 3‐dipolar
cycloaddition reaction between terminal acetylenes and azides) has vastly increased in …