Separation and purification of hydrocarbons with porous materials

Y Wu, BM Weckhuysen - Angewandte Chemie International …, 2021 - Wiley Online Library
This Minireview focuses on the developments of the adsorptive separation of
methane/nitrogen, ethene/ethane, propene/propane mixtures as well as on the separation of …

Designed metal-organic frameworks with potential for multi-component hydrocarbon separation

L Wang, H Huang, X Zhang, H Zhao, F Li… - Coordination Chemistry …, 2023 - Elsevier
Petrochemical-related gases, especially light hydrocarbons with 1–8 carbon atoms, are
essential industrial feedstocks. However, during steam cracking they inevitably coexist with …

Fine pore engineering in a series of isoreticular metal-organic frameworks for efficient C2H2/CO2 separation

J Wang, Y Zhang, Y Su, X Liu, P Zhang, RB Lin… - Nature …, 2022 - nature.com
The separation of C2H2/CO2 is not only industrially important for acetylene purification but
also scientifically challenging owing to their high similarities in physical properties and …

Discrimination of xylene isomers in a stacked coordination polymer

L Li, L Guo, DH Olson, S Xian, Z Zhang, Q Yang, K Wu… - Science, 2022 - science.org
The separation and purification of xylene isomers is an industrially important but challenging
process. Developing highly efficient adsorbents is crucial for the implementation of …

Tunable confined aliphatic pore environment in robust metal–organic frameworks for efficient separation of gases with a similar structure

J Zhou, T Ke, F Steinke, N Stock, Z Zhang… - Journal of the …, 2022 - ACS Publications
The fine-tuning of the pore structure of metal–organic frameworks (MOFs) is of critical
importance to developing energy-efficient processes for the challenging separation of …

Reverse-selective metal–organic framework materials for the efficient separation and purification of light hydrocarbons

SQ Yang, TL Hu - Coordination Chemistry Reviews, 2022 - Elsevier
The separation and purification process of hydrocarbons is one of the crucial and daunting
challenges in the petrochemistry field, which is widely depended on cryogenic distillation by …

A review on anion-pillared metal–organic frameworks (APMOFs) and their composites with the balance of adsorption capacity and separation selectivity for efficient …

X Li, H Bian, W Huang, B Yan, X Wang, B Zhu - Coordination Chemistry …, 2022 - Elsevier
Metal-organic frameworks (MOFs) have gained widespread attention in many fields,
especially in gas adsorption and separation. However, traditional MOFs always suffer from a …

Analysis and Refinement of Host–Guest Interactions in Metal–Organic Frameworks

Y Chen, W Lu, M Schröder… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Metal–organic frameworks (MOFs) are a class of hybrid porous materials
characterized by their periodic assembly using metal ions and organic ligands through …

Control of the pore chemistry in metal-organic frameworks for efficient adsorption of benzene and separation of benzene/cyclohexane

Y Han, Y Chen, Y Ma, J Bailey, Z Wang, D Lee… - Chem, 2023 - cell.com
Benzene is an important air pollutant and a key chemical feedstock for the synthesis of
cyclohexane. Because of the small difference of 0.6° C in their boiling points, the separation …

Recent advances in microporous metal–organic frameworks as promising adsorbents for gas separation

JX Wang, CC Liang, XW Gu, HM Wen… - Journal of Materials …, 2022 - pubs.rsc.org
Gas separation is a crucial process for the production of many highly valuable chemical
feedstocks in the petrochemical industry. Traditional separation technologies, including …