Synthetic analogues relevant to the structure and function of zinc enzymes

G Parkin - Chemical Reviews, 2004 - ACS Publications
Zinc is essential to all forms of life, 1-4 with an average adult human containing ca. 3 g of
zinc. 5 For example, zinc is indispensable for effective growth and development, has …

Stereochemical Aspects of Metal Xanthate Complexes: Molecular Structures and Supramolecular Self‐Assembly

ERT Tiekink, I Haiduc - Progress in Inorganic Chemistry, 2005 - Wiley Online Library
The alkyl esters of dithiocarbonic acid, ie,(RO) C (= S) SH, are unstable but, their metal salts
and complexes are generally stable and present both practical and academic interest. Thus …

[图书][B] Scorpionates: the coordination chemistry of polypyrazolylborate ligands

S Trofimenko - 1999 - books.google.com
This book deals with polypyrazolylborates (scorpionates), a class of ligands known since
1966, but becoming rapidly popular with inorganic, organometallic and coordination …

Transitions, transition states, transition state analogues: Zinc pyrazolylborate chemistry related to zinc enzymes

H Vahrenkamp - Accounts of chemical research, 1999 - ACS Publications
Zinc is known to be functional in almost 300 enzymes representing all subgroups of the
enzyme classification. 1 Although it is present in organisms only about half as much as its …

Valence tautomerism in a high-valent manganese–oxo porphyrinoid complex induced by a lewis acid

P Leeladee, RA Baglia, KA Prokop… - Journal of the …, 2012 - ACS Publications
Addition of the Lewis acid Zn2+ to (TBP8Cz) MnV (O) induces valence tautomerization,
resulting in the formation of [(TBP8Cz+•) MnIV (O)–Zn2+]. This new species was …

Hydrosulfide complexes of the transition elements: diverse roles in bioinorganic, cluster, coordination, and organometallic chemistry

MD Pluth, ZJ Tonzetich - Chemical Society Reviews, 2020 - pubs.rsc.org
Sulfur-based ligands are versatile donors that play important roles in a wide array of
subdisciplines of inorganic chemistry including organometallic chemistry, bioinorganic …

Approaching Angstrom-Scale Resolution in Lithography Using Low-Molecular-Mass Resists (< 500 Da)

MSM Saifullah, AK Rajak, KA Hofhuis, N Tiwale… - ACS …, 2024 - ACS Publications
Resists that enable high-throughput and high-resolution patterning are essential in driving
the semiconductor technology forward. The ultimate patterning performance of a resist in …

Low-Coordinate Magnesium Sulfide and Selenide Complexes

S Burnett, R Ferns, DB Cordes, AMZ Slawin… - Inorganic …, 2023 - ACS Publications
The reactions of [{(iPrDipNacNac) Mg} 2] 1 (iPrDipnacnac= HC (iPrCNDip) 2) with Ph3P═ O
at 100° C afforded the phosphinate complex [(iPrDipNacNac) Mg (OPPh3)(OPPh2)] 3 …

Hydrosulfido complexes of transition metals

S Kuwata, M Hidai - Coordination Chemistry Reviews, 2001 - Elsevier
Interest in hydrosulfido (SH) complexes stems from their relevance to metalloenzymes and
metal sulfide catalysts for industrial hydrodesulfurization. This review provides an overview …

Protonation and Reactivity towards Carbon Dioxide of the Mononuclear Tetrahedral Zinc and Cobalt Hydroxide Complexes, [TpBut,Me]ZnOH and [TpBut,Me] …

C Bergquist, T Fillebeen, MM Morlok… - Journal of the American …, 2003 - ACS Publications
The tris (3-tert-butyl-5-methylpyrazolyl) hydroborato zinc hydroxide complex [TpBut, Me]
ZnOH is protonated by (C6F5) 3B (OH2) to yield the aqua derivative {[TpBut, Me] Zn …