The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

From enhanced diffusion to ultrafast ballistic motion of hybrid light–matter excitations

M Balasubrahmaniyam, A Simkhovich, A Golombek… - Nature Materials, 2023 - nature.com
Transport of excitons and charge carriers in molecular systems can be enhanced by
coherent coupling to photons, giving rise to the formation of hybrid excitations known as …

Dynamics of excitons in conjugated molecules and organic semiconductor systems

OP Dimitriev - Chemical Reviews, 2022 - ACS Publications
The exciton, an excited electron–hole pair bound by Coulomb attraction, plays a key role in
photophysics of organic molecules and drives practically important phenomena such as …

Cavity-enhanced energy transport in molecular systems

G Sandik, J Feist, FJ García-Vidal, T Schwartz - Nature Materials, 2024 - nature.com
Molecules are the building blocks of all of nature's functional components, serving as the
machinery that captures, stores and releases energy or converts it into useful work …

Theoretical challenges in polaritonic chemistry

J Fregoni, FJ Garcia-Vidal, J Feist - ACS photonics, 2022 - ACS Publications
Polaritonic chemistry exploits strong light–matter coupling between molecules and confined
electromagnetic field modes to enable new chemical reactivities. In systems displaying this …