Corrosion of zirconium alloys used for nuclear fuel cladding

AT Motta, A Couet, RJ Comstock - Annual Review of Materials …, 2015 - annualreviews.org
During operation, nuclear fuel rods are immersed in the primary water, causing waterside
corrosion and consequent hydrogen ingress. In this review, the mechanisms of corrosion …

Investigating zirconium alloy corrosion with advanced experimental techniques: A review

E Kautz, B Gwalani, Z Yu, T Varga, K Geelhood… - Journal of Nuclear …, 2023 - Elsevier
Zirconium-based alloys (Zr alloys) are key materials in the nuclear industry due to their
thermal stability, mechanical durability, and low thermal neutron cross section. However …

Thermodynamics of the Zr-O system from first-principles calculations

B Puchala, A Van der Ven - Physical Review B—Condensed Matter and …, 2013 - APS
We investigate the electronic and thermodynamic properties of Zr and its oxides from first
principles to elucidate phase stability in the Zr-O system. Hexagonally close-packed Zr is …

How the crystallography and nanoscale chemistry of the metal/oxide interface develops during the aqueous oxidation of zirconium cladding alloys

N Ni, D Hudson, J Wei, P Wang, S Lozano-Perez… - Acta Materialia, 2012 - Elsevier
Aqueous corrosion and hydrogenation have become major limiting factors to the use of
zirconium alloys as fuel cladding and assembly components in water-cooled nuclear …

Atom probe tomography study of alloying element distributions in Zr alloys and their oxides

Y Dong, AT Motta, EA Marquis - Journal of Nuclear Materials, 2013 - Elsevier
A detailed study of alloying element distributions in the metal and oxygen rich regions of
corroded Zr alloys and of the phases formed ahead of the oxide front was conducted using …

Transparent high-strength nanosized yttria stabilized zirconia obtained by pressure-less sintering

O Akhlaghi, E Camposilvan, Z Goharibajestani… - Journal of the European …, 2022 - Elsevier
This work describes the development of transparent high-strength Yttria-Stabilized Zirconia
(YSZ) ceramics with ultra-fine grain size utilizing conventional pressure-less densification …

Crystal structure of the ZrO phase at zirconium/zirconium oxide interfaces

RJ Nicholls, N Ni, S Lozano‐Perez… - Advanced …, 2015 - Wiley Online Library
Zirconium‐based alloys are used in water‐cooled nuclear reactors for both nuclear fuel
cladding and structural components. Under this harsh environment, the main factor limiting …

Identifying suboxide grains at the metal–oxide interface of a corroded Zr–1.0% Nb alloy using (S) TEM, transmission-EBSD and EELS

J Hu, A Garner, N Ni, A Gholinia, RJ Nicholls… - Micron, 2015 - Elsevier
Here we report a methodology combining TEM, STEM, Transmission-EBSD and EELS to
analyse the structural and chemical properties of the metal–oxide interface of corroded Zr …

Generation of electric-field stabilized zirconium monoxide secondary phase within cubic zirconia

H Charalambous, SK Jha, JS Okasinski, T Tsakalakos - Scripta Materialia, 2021 - Elsevier
Flash sintering of cubic yttria-stabilized zirconia has been studied via in situ energy
dispersive diffraction. A secondary rocksalt-phase zirconium monoxide was observed …

[HTML][HTML] A study into stress relaxation in oxides formed on zirconium alloys

P Platt, E Polatidis, P Frankel, M Klaus, M Gass… - Journal of Nuclear …, 2015 - Elsevier
Pressurised and boiling water reactors contain zirconium alloys, which are used as nuclear
fuel cladding. Oxidation of these alloys, and the associated hydrogen pick-up, is a limiting …