Stereodivergent catalysis

IP Beletskaya, C Najera, M Yus - Chemical reviews, 2018 - ACS Publications
This review covers diastereo-and enantiodivergent catalyzed reactions in acyclic and cyclic
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …

Asymmetric catalysis using chiral salen–metal complexes: recent advances

S Shaw, JD White - Chemical reviews, 2019 - ACS Publications
Chiral salen–metal complexes are among the most versatile asymmetric catalysts and have
found utility in fields ranging from materials chemistry to organic synthesis. These complexes …

Squaramides: bridging from molecular recognition to bifunctional organocatalysis

J Alemán, A Parra, H Jiang… - Chemistry–A European …, 2011 - Wiley Online Library
In this minireview, squaramides are presented from their roots as artificial anion receptors in
molecular recognition studies to their recent advances as powerful bifunctional hydrogen …

Nitro-mannich reaction

A Noble, JC Anderson - Chemical Reviews, 2013 - ACS Publications
Reactions that utilize addition of active C− H nucleophiles to C X bonds represent some of
the most fundamental carbon− carbon bond-forming processes in organic chemistry. Of …

Synthetic approaches to 3-(2-nitroalkyl) indoles and their use to access tryptamines and related bioactive compounds

S Lancianesi, A Palmieri, M Petrini - Chemical Reviews, 2014 - ACS Publications
The assembly of architecturally complex alkaloids embedding the indole nucleus is of
paramount importance for the target oriented synthesis of biologically active molecules. 1 A …

Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes

S Matsunaga, M Shibasaki - Chemical Communications, 2014 - pubs.rsc.org
Cooperative catalysis has proven to be a powerful strategy for realizing high reactivity and
selectivity in asymmetric transformations. A variety of cooperative asymmetric catalysts have …

Cinchona alkaloids in asymmetric organocatalysis

T Marcelli, H Hiemstra - Synthesis, 2010 - thieme-connect.com
This article reviews the applications of cinchona alkaloids as asymmetric catalysts. In the last
few years, characterized by the resurgence of interest in asymmetric organocatalysis …

Umpolung reactivity in amide and peptide synthesis

B Shen, DM Makley, JN Johnston - Nature, 2010 - nature.com
The amide bond is one of nature's most common functional and structural elements, as the
backbones of all natural peptides and proteins are composed of amide bonds. Amides are …

Recent applications of Cinchona alkaloids and their derivatives as catalysts in metal-free asymmetric synthesis

EMO Yeboah, SO Yeboah, GS Singh - Tetrahedron, 2011 - Elsevier
The Cinchona alkaloids are natural products found in the bark of trees of the genus
Cinchona. The genus comprises about 40 species of trees or shrubs in the family Rubiaceae …

Chiral tetraaminophosphonium salt-mediated asymmetric direct Henry reaction

D Uraguchi, S Sakaki, T Ooi - Journal of the American Chemical …, 2007 - ACS Publications
Chiral tetraaminophosphonium salts 1 possessing the phosphorus-centered [5.5]-spirocyclic
core have been designed and synthesized in a single step from l-valine-derived diamine …