In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …

Criegee intermediates are reactive species formed in the ozonolysis of alkenes. Their
subsequent chemistry is critical to an accounting of OH production, aerosol formation, and …

Isoprene has the highest emission into Earth's atmosphere of any nonmethane hydrocarbon.
Atmospheric processing of alkenes, including isoprene, via ozonolysis leads to the formation …

Ozonolysis of isoprene is considered to be an important source of formic acid (HCOOH), but
its underlying reaction mechanisms related to HCOOH formation are poorly understood …

Criegee intermediates are reactive intermediates that are implicated in transforming the
composition of Earth's troposphere and in the formation of secondary organic aerosol …

The fates of organic hydroperoxides (ROOHs) in atmospheric condensed phases are key to
understanding the oxidative and toxicological potentials of particulate matter. Recently …

Criegee intermediates are important oxidants produced in the ozonolysis of alkenes in the
atmosphere. Quantitative kinetics of the reactions of Criegee intermediates are required for …

Trifluoroacetic acid (TFA), a highly soluble and stable organic acid, is photochemically
produced by certain anthropogenically emitted halocarbons such as HFC-134a and HFO …

Chemical mechanisms form the core of atmospheric models to describe degradation
pathways of pollutants and ultimately inform air quality and climate policymakers and other …

1, 2, 4-Trioxolanes, known as secondary ozonides (SOZs), are key products of ozonolysis of
biogenic terpenoids. Functionalized terpenoid-derived SOZs are readily taken up into …