Tuning hydrogenation chemistry of Pd-based heterogeneous catalysts by introducing homogeneous-like ligands

J Zhang, W Hu, B Qian, H Li, B Sudduth… - Nature …, 2023 - nature.com
Noble metals have been extensively employed in a variety of hydrotreating catalyst systems
for their featured functionality of hydrogen activation but may also bring side reactions such …

Silver-induced adsorption optimization of adjacent Co tetrahedral sites for enhanced oxygen reduction/evolution reaction

CW Yu, CY Du, T Ouyang, XT Zhang, ZQ Liu - Chemical Engineering …, 2023 - Elsevier
Physical structure change of catalysts based on the electronic metal-support interaction
(EMSI) effects is a prospective strategy to regulate the surface electronic structure of …

Self-assembled synthesis of Pd/SPEn from polyelectrolyte membranes for efficient direct synthesis of H2O2 via inhibiting the dissociation of O− O bond

E Ye, Z Chen, Y Shi, D Zhang, W Li, H Qin, Z Luo… - Chemical Engineering …, 2023 - Elsevier
Although a high-activity yield of hydrogen peroxide (H 2 O 2) can be achieved by direct
synthesis from hydrogen and oxygen, developing an extreme catalyst with high activity and …

Breaking the Limit of Size-Dependent CO2RR Selectivity in Silver Nanoparticle Electrocatalysts through Electronic Metal–Carbon Interactions

X Deng, D Alfonso, TD Nguyen-Phan… - ACS Catalysis, 2023 - ACS Publications
We demonstrate that electronic metal–support interactions (EMSIs) between silver and
carbon can dramatically improve the CO2 reduction reaction (CO2RR) performance of the …

Metal–Sulfur Interfaces as the Primary Active Sites for Catalytic Hydrogenations

W Chen, Y Che, J Xia, L Zheng, H Lv… - Journal of the …, 2024 - ACS Publications
The determination of catalytically active sites is crucial for understanding the catalytic
mechanism and providing guidelines for the design of more efficient catalysts. However, the …

Interfacial electronic structure modulation between Pd and N-containing support for efficient formic acid dehydrogenation

N Lu, B Liu, Z Peng, J Sui, X Zhang, Y Ma, R Li… - International Journal of …, 2024 - Elsevier
Rational design and fabrication of catalysts with excellent efficiency, high selectivity and
outstanding stability is of great significance for the practical application of formic acid …

Graphene Chainmail Shelled Dilute Ni─ Cu Alloy for Selective and Robust Aqueous Phase Catalytic Hydrogenation

H Yuan, M Hong, X Huang, W Qiu, F Dong… - Advanced …, 2024 - Wiley Online Library
Cost‐effective non‐noble metal‐based catalysts for selective hydrogenation with excellent
activity, selectivity, and durability are still the holy grail. Herein, an oxygen‐doped carbon …

Multilevel assault dominated by electron-transfer nonradical pathway via electronic metal–support interactions of Bi-C bonds for disinfection

R Zhang, G Xu, Z Tang, J Mei, M Hu, D Ma… - Chemical Engineering …, 2024 - Elsevier
Multilevel assaults on aqueous pathogenic microorganisms were realized by persulfate (PS)
activation system with Bi–C based electronic metal-supported interactions (EMSI) of bismuth …

Pd/N-doped carbon dots@ dendritic mesoporous silica nanospheres: A highly efficient catalyst for the hydrogenation of 4-nitrophenol

W Liu, Y Zhu, J Wang, H Feng, Y Zhai, W Li, D Zhao - Nano Research, 2024 - Springer
Highly dispersed Pd/N-doped carbon dots (Pd/NCDs) were successfully immobilized in the
mesoporous channels of amino-functionalized dendritic mesoporous silica nanospheres …

Pd/oCNT monolithic catalysts for continuous-flow selective hydrogenation of cinnamaldehyde

Q Zhang, Y Ma, J Ma, C Meng, S Luo… - ACS Applied Nano …, 2023 - ACS Publications
Chemical engineering optimization from a batch process to continuous flow in liquid-phase
hydrogenation brings a significant improvement in efficiency. However, its further application …