Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

The present paper comprehensively reviews group 3–7 metal NHC complexes reported
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …

Triazole-derived N-heterocyclic carbenes, triazolylidenes (trz) have become an interesting
alternative to the ubiquitous Arduengo-type imidazole-derived carbenes, in part because …

Rigid terdentate 'pincer'ligands containing a bridgehead N-heterocyclic carbene (NHC)
donor attract considerable interest as spectators in transition metal complexes with broad …

The chemistry of NHC core pincer ligands of LX2 type bearing two pending arms, identical
or not, whose coordinating center is anionic in nature, is here reviewed. In this family, the …

This work reports on the synthesis and in-depth electrochemical and photochemical
characterization of two chromium (0) and molydenum (0) metal complexes with bidentate …

We report the synthesis of vanadium (V) oxo complex 1 with a pincer-type dianionic
mesoionic carbene (MIC) ligand L 1 and the general formula [VOCl (L1)]. A comparison of …

The high-valent molybdenum (VI) N-heterocyclic carbene complexes,(NHC) MoO2 (1) and
(NHC) MoO (NtBu)(2)(NHC= 1, 3-bis (3, 5-di-tert-butyl-2-phenolato)-benzimidazol-2 …

Reaction between a carbazole-based mesoionic carbene ligand and manganese (II) iodide
results in the formation of a rare air-stable manganese (IV) complex after aerobic workup …

The chemistry of N-heterocyclic carbenes with Earth-abundant manganese has largely
focused on low-valent systems for reductive catalysis. Here, we have decorated imidazole …