Frontal polymerizations: from chemical perspectives to macroscopic properties and applications

BA Suslick, J Hemmer, BR Groce, KJ Stawiasz… - Chemical …, 2023 - ACS Publications
The synthesis and processing of most thermoplastics and thermoset polymeric materials rely
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …

Advances in frontal polymerization strategy: From fundamentals to applications

Q Li, HX Shen, C Liu, CF Wang, L Zhu… - Progress in Polymer …, 2022 - Elsevier
Polymer materials have sparked considerable interest from both academic and industrial
researchers due to their fantastic features and wide applications. The polymer synthetic …

[图书][B] An introduction to nonlinear chemical dynamics: oscillations, waves, patterns, and chaos

IR Epstein, JA Pojman - 1998 - books.google.com
Just a few decades ago, chemical oscillations were thought to be exotic reactions of only
theoretical interest. Now known to govern an array of physical and biological processes …

Free-radical polymerizations of and in deep eutectic solvents: Green synthesis of functional materials

JD Mota-Morales, RJ Sánchez-Leija, A Carranza… - Progress in Polymer …, 2018 - Elsevier
The increasing environmental awareness has led to the search for alternative reaction
media to reduce or eliminate the use of organic solvents in polymer science. Deep eutectic …

Additive manufacturing solidification methodologies for ink formulation

X Xu, J Yang, W Jonhson, Y Wang, A Suwardi… - Additive …, 2022 - Elsevier
With the burgeoning interest in 3D printing for complex and high-resolution patterned
devices, ink formulation plays a vital role for its successful utilization in various application in …

Photopolymerization processes of thick films and in shadow areas: A review for the access to composites

P Garra, C Dietlin, F Morlet-Savary, F Dumur… - Polymer …, 2017 - pubs.rsc.org
The photopolymerization processes are currently associated with thin samples for which the
light penetration is good enough to activate the photoinitiator or the photoinitiating system for …

Autocatalysis: Kinetics, mechanisms and design

AI Hanopolskyi, VA Smaliak, AI Novichkov… - …, 2021 - Wiley Online Library
The importance of autocatalysis spans from practical applications such as in chemically
amplified photoresists, to autocatalysis playing a fundamental role in evolution as well as a …

Free-radical frontal polymerization: Self-propagating thermal reaction waves

JA Pojman, VM Ilyashenko, AM Khan - Journal of the Chemical Society …, 1996 - pubs.rsc.org
Frontal polymerization is a mode of converting monomer into polymer via a localized
reaction zone that propagates. Such fronts can exist with free-radical polymerization or …

Graphene-containing thermoresponsive nanocomposite hydrogels of poly (N-isopropylacrylamide) prepared by frontal polymerization

V Alzari, D Nuvoli, S Scognamillo, M Piccinini… - Journal of Materials …, 2011 - pubs.rsc.org
Frontal polymerization has been successfully used to synthesize poly (N-
isopropylacrylamide) nanocomposite hydrogels containing graphene. The latter was directly …

Frontal ring-opening metathesis polymerization of dicyclopentadiene

A Mariani, S Fiori, Y Chekanov, JA Pojman - Macromolecules, 2001 - ACS Publications
Introduction. Frontal polymerization entails the conversion of a monomer into a polymer via a
localized exothermic reaction zone that propagates through the coupling of thermal diffusion …