Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

The efficacy and synthetic versatility of asymmetric organocatalysis have contributed
enormously to the field of organic synthesis since the early 2000s. As asymmetric …

Phosphorus-based organocatalysis encompasses several subfields that have undergone
rapid growth in recent years. This Outlook gives an overview of its various aspects. In …

A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …

Asymmetric hydroalkoxylation of alkenes constitutes a redox-neutral and 100% atom-
economical strategy toward enantioenriched oxygenated building blocks from readily …

A synthetic method for the reductive transformation of nitroarenes into ortho-aminated and-
annulated products is reported. The method operates via the exhaustive deoxygenation of …

Conspectus In recent years, nickel-catalyzed asymmetric coupling reactions have emerged
as efficient methods for constructing chiral C (sp3) carbon centers. Numerous novel …

In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective
catalytic methods powered by electricity remain rare. In this work, we report the development …

The synthesis of tertiary phosphines (III) has been a long-standing challenge in synthetic
chemistry because of inevitable issues including harsh conditions, sensitive organometallic …

Organophosphine catalysis of allenoates has doubtlessly been one of the most ideal and
powerful synthetic strategies for the generation of highly functionalized carbo-/hetero-cycle …