Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Over the last 15 years, a plethora of research has provided major insights into the structure
and function of hydrogenase enzymes. This has led to the important development of …

Interconversion of water and hydrogen in unitized regenerative fuel cells is a promising
energy storage framework for smoothing out the temporal fluctuations of solar and wind …

This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

Conspectus The [FeFe] hydrogenases (H2ases) catalyze the redox reaction that
interconverts protons and H2. This area of biocatalysis has attracted attention because the …

Generation of hydrogen by reduction of two protons by two electrons can be catalysed by
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …

This article reviews published literature on the electrochemical reduction and oxidation of
complexes containing the Fe2S2 core characteristic of the active site of [FeFe] …

Bioorganometallic chemistry's beginnings 25 years ago were timid, modest and sporadic,
overshadowed by the supremacy of organometallic catalysis at that time. Its development …

Conspectus Over the past two decades, the bioinorganic chemistry of hydrogenases has
attracted much interest from basic and applied research. Hydrogenases are highly efficient …