The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity

N Lehnert, E Kim, HT Dong, JB Harland… - Chemical …, 2021 - ACS Publications
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Copper active sites in biology

EI Solomon, DE Heppner, EM Johnston… - Chemical …, 2014 - ACS Publications
On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …

Selective methanol‐to‐formate electrocatalytic conversion on branched nickel carbide

J Li, R Wei, X Wang, Y Zuo, X Han, J Arbiol… - Angewandte …, 2020 - Wiley Online Library
A methanol economy will be favored by the availability of low‐cost catalysts able to
selectively oxidize methanol to formate. This selective oxidation would allow extraction of the …

Catalysis and Electron Transfer in De Novo Designed Metalloproteins

KJ Koebke, TBJ Pinter, WC Pitts, VL Pecoraro - Chemical reviews, 2022 - ACS Publications
One of the hallmark advances in our understanding of metalloprotein function is showcased
in our ability to design new, non-native, catalytically active protein scaffolds. This review …

Protein design: toward functional metalloenzymes

F Yu, VM Cangelosi, ML Zastrow, M Tegoni… - Chemical …, 2014 - ACS Publications
Protein design is a valuable tool for understanding the fundamental factors that dictate
protein structure and function. The field of protein design has seen significant progress over …

Fully biodegradable and long-term operational primary zinc batteries as power sources for electronic medicine

X Huang, H Hou, B Yu, J Bai, Y Guan, L Wang… - ACS …, 2023 - ACS Publications
Given the advantages of high energy density and easy deployment, biodegradable primary
battery systems remain as a promising power source to achieve bioresorbable electronic …

How biology handles nitrite

LB Maia, JJG Moura - Chemical Reviews, 2014 - ACS Publications
Nitrite is one of the players in the broad nitrogen biogeochemical cycle. This nitrogen oxo-
anion is involved in key pathways crucial to life on Earth and to the planetary “recycling” of …

The emerging biology of the nitrite anion

MT Gladwin, AN Schechter, DB Kim-Shapiro… - Nature chemical …, 2005 - nature.com
Nitrite has now been proposed to play an important physiological role in signaling, blood
flow regulation and hypoxic nitric oxide homeostasis. A recent two-day symposium at the US …

Enzymatic function of hemoglobin as a nitrite reductase that produces NO under allosteric control

Z Huang, S Shiva, DB Kim-Shapiro… - The Journal of …, 2005 - Am Soc Clin Investig
Hypoxic vasodilation is a fundamental, highly conserved physiological response that
requires oxygen and/or pH sensing coupled to vasodilation. While this process was first …

In situ electrochemical generation of nitric oxide for neuronal modulation

J Park, K Jin, A Sahasrabudhe, PH Chiang… - Nature …, 2020 - nature.com
Understanding the function of nitric oxide, a lipophilic messenger in physiological processes
across nervous, cardiovascular and immune systems, is currently impeded by the dearth of …