Hydrides of the main-group metals: New variations on an old theme

S Aldridge, AJ Downs - Chemical reviews, 2001 - ACS Publications
For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …

How to determine structures when single crystals cannot be grown: opportunities for structure determination of molecular materials using powder diffraction data

KDM Harris, EY Cheung - Chemical Society Reviews, 2004 - pubs.rsc.org
Many crystalline solids cannot be prepared as single crystals of sufficient size and/or quality
for structure determination to be carried out using single crystal X-ray diffraction techniques …

Growth of group III nitrides. A review of precursors and techniques

DA Neumayer, JG Ekerdt - Chemistry of materials, 1996 - ACS Publications
The AlGaInN quaternary alloy system is uniquely suited for numerous device applications
because the bandgap can be varied from 1.9 to 6.2 eV by changing the alloy composition …

A reaction-transport model for AlGaN MOVPE growth

TG Mihopoulos, V Gupta, KF Jensen - Journal of Crystal Growth, 1998 - Elsevier
We present a systematic study of the complex chemistry and transport phenomena
underlying metalorganic vapor phase epitaxy (MOVPE) of AlGaN; in particular, the …

Nature of the parasitic chemistry during AlGaInN OMVPE

JR Creighton, GT Wang, WG Breiland… - Journal of crystal growth, 2004 - Elsevier
Using in situ laser light scattering, we have observed gas-phase nanoparticles formed
during AlN, GaN and InN OMVPE. The response of the scattering intensity to a wide range of …

Structural and spectroscopic characterization of the compounds [Al (NMe2) 3] 2,[Ga (NMe2) 3] 2,[(Me2N) 2Al {μ-N (H) 1-Ad}] 2 (1-Ad= 1-adamantanyl) and [{Me (μ …

KM Waggoner, MM Olmstead, PP Power - Polyhedron, 1990 - Elsevier
Abstract The compounds [Al (NMe 2) 3] 2 (1),[Ga (NMe 2) 3] 2 (2),[(Me 2 N) 2 Al {μ-N (H) 1-
Ad}] 2 (3) and [{Me (μ-NPh 2) Al} 2 NPh (μ-C 6 H 4)]· 0.5 PhMe (4) have been structurally …

Chemistry of alkoxide precursors

RC Mehrotra - Journal of non-crystalline solids, 1990 - Elsevier
In view of the increasing applications of metal alkoxides as precursors for ceramics, the
physicochemical aspects of successive steps in the SSG process are being intensively …

Chemical vapor deposition of gallium sulfide: phase control by molecular design

AN MacInnes, MB Power, AR Barron - Chemistry of materials, 1993 - ACS Publications
Gallium sulfide (GaS) thin films have been grown at 380-420 C by atmospheric pressure
metal-organic chemical vapor deposition (MOCVD) using the single-source precursors [('Bu) …

Coordination compounds of aluminum as precursors to aluminum nitride

FC Sauls, LV Interrante - Coordination chemistry reviews, 1993 - Elsevier
Two different systems have been examined as potential sources of aluminum nitride, an
important electronic and structural ceramic material. Cyclic organoaluminum amides …

Utility of Arylamido Ligands in Yttrium and Lanthanide Chemistry1

WJ Evans, MA Ansari, JW Ziller, SI Khan - Inorganic chemistry, 1996 - ACS Publications
The reactivity of KNHAr reagents (Ar= C6H5, C6H3Me2-2, 6, C6H3iPr2-2, 6) with lanthanide
and yttrium trichlorides has been investigated. With the larger metals Nd and Sm and the …