Diamond Formation via Carbonate or CO2 Reduction under Pressures and Temperatures of the Lithospheric Mantle: Review of Experimental Data

YV Bataleva, YN Palyanov - Minerals, 2023 - mdpi.com
Existing ideas about the polygenic origin of diamonds in nature involve various processes,
mechanisms, and driving forces for diamond crystallization, including redox reactions …

Synthesis of calcium orthocarbonate, Ca2CO4-Pnma at PT conditions of Earth's transition zone and lower mantle

J Binck, D Laniel, L Bayarjargal… - American …, 2022 - degruyter.com
We show, by single-crystal diffraction studies in laser-heated diamond-anvil cells, that
Ca2CO4 orthocarbonate, which contains CO44− tetrahedra, can be formed already at~ 20 …

Fate of Carbonates in the Earth's Mantle (10-136 GPa)

J Gao, X Wu, X Yuan, W Su - Frontiers in Earth Science, 2022 - frontiersin.org
Earth carbon cycle shapes the evolution of our planet and our habitats. As a key region of
carbon cycle, subduction zone acts as a sole channel transporting supracrustal carbonate …

Carbonate stability in the reduced lower mantle

SM Dorfman, J Badro, F Nabiei, VB Prakapenka… - Earth and Planetary …, 2018 - Elsevier
Carbonate minerals are important hosts of carbon in the crust and mantle with a key role in
the transport and storage of carbon in Earth's deep interior over the history of the planet …

Phase stabilities of and -II studied by Raman spectroscopy, x-ray diffraction, and density functional theory calculations

J Binck, L Bayarjargal, SS Lobanov, W Morgenroth… - Physical Review …, 2020 - APS
Carbonates are the major hosts of carbon on Earth's surface and their fate during subduction
needs to be known to understand the deep carbon cycle. Magnesite (MgCO 3) is thought to …

Calcium orthocarbonate, Ca2CO4-Pnma: A potential host for subducting carbon in the transition zone and lower mantle

D Sagatova, A Shatskiy, N Sagatov, PN Gavryushkin… - Lithos, 2020 - Elsevier
A novel structure of calcium orthocarbonate Ca 2 CO 4-Pnma has been discovered using ab-
initio crystal structure prediction methods (AIRSS and USPEX) based on the density …

Pyroxene-carbonate reactions in the CaMgSi2O6 ± NaAlSi2O6 + MgCO3 ± Na2CO3 ± K2CO3 system at 3–6 GPa: Implications for partial melting of …

A Shatskiy, IV Podborodnikov, AV Arefiev… - … to Mineralogy and …, 2021 - Springer
The reactions between pyroxenes and carbonates have been studied in the CaMgSi 2 O 6+
MgCO 3 (Di+ 2Mgs), CaMgSi 2 O 6+ NaAlSi 2 O 6+ 2MgCO 3 (Di+ Jd+ 2Mgs), CaMgSi 2 O …

How do diamonds grow in metal melt together with silicate minerals? An experimental study of diamond morphology

A Chepurov, V Sonin, JM Dereppe… - European Journal of …, 2020 - ejm.copernicus.org
The origin and evolution of metal melts in the Earth's mantle and their role in the formation of
diamond are the subject of active discussion. It is widely accepted that portions of metal …

Carbon-bearing magmas in the Earth's deep interior

KD Litasov, A Shatskiy - Magmas Under Pressure, 2018 - Elsevier
Geodynamic models considering fast mantle upwelling without volatile-bearing components
are inapplicable due to high melting temperatures of mantle silicates. Here we discuss the …

[HTML][HTML] Genetic link between saline and carbonatitic mantle fluids: The system NaCl-CaCO3-MgCO3±H2O±Fe0 at 6 GPa

A Shatskiy, IV Podborodnikov, AV Arefiev… - Geoscience …, 2022 - Elsevier
Melt inclusions in kimberlitic minerals and diamonds indicate that chlorides are important
constituents of mantle carbonatite melts. Besides, alkaline chlorides are important …