The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …
physiological and pathological events in biology. Metal coordination chemistry, especially …
Distortion of the [FeNO]2 Core in Flavodiiron Nitric Oxide Reductase Models Inhibits N–N Bond Formation and Promotes Formation of Unusual Dinitrosyl Iron …
CJ White, MO Lengel, AJ Bracken… - Journal of the …, 2022 - ACS Publications
Flavodiiron nitric oxide reductases (FNORs) carry out the reduction of nitric oxide (NO) to
nitrous oxide (N2O), allowing infectious pathogens to mitigate toxic levels of NO generated …
nitrous oxide (N2O), allowing infectious pathogens to mitigate toxic levels of NO generated …
Photodynamic treatment of acute vascular occlusion by using an iron–nitrosyl complex
Retinal vascular occlusion (RVO) is a common cause of visual impairment. Although several
approaches, including vasodilators, have been explored to treat retinal vascular occlusion …
approaches, including vasodilators, have been explored to treat retinal vascular occlusion …
Photoinduced NO and HNO Production from Mononuclear {FeNO}6 Complex Bearing a Pendant Thiol
CK Chiang, KT Chu, CC Lin, SR Xie… - Journal of the …, 2020 - ACS Publications
Light triggers the formation of HNO from a metal–nitrosyl species, facilitated by an
intramolecular pendant thiol proton. Two {FeNO} 6 complexes (the Enemark–Felthan …
intramolecular pendant thiol proton. Two {FeNO} 6 complexes (the Enemark–Felthan …
Cooperative redox and spin activity from three redox congeners of sulfur-bridged iron nitrosyl and nickel dithiolene complexes
M Quiroz, MM Lockart, MR Saber… - Proceedings of the …, 2022 - National Acad Sciences
The synthesis of sulfur-bridged Fe–Ni heterobimetallics was inspired by Nature's strategies
to “trick” abundant first row transition metals into enabling 2-electron processes: redox-active …
to “trick” abundant first row transition metals into enabling 2-electron processes: redox-active …
A Nonheme Mononuclear {FeNO}7 Complex that Produces N2O in the Absence of an Exogenous Reductant
A new nonheme iron (II) complex, FeII (Me3TACN)((OSiPh2) 2O)(1), is reported. Reaction of
1 with NO (g) gives a stable mononitrosyl complex Fe (NO)(Me3TACN)((OSiPh2) 2O)(2) …
1 with NO (g) gives a stable mononitrosyl complex Fe (NO)(Me3TACN)((OSiPh2) 2O)(2) …
Light‐induced NO release from iron‐nitrosyl‐thiolato complex: The role of noncovalent thiol/thioether
HC Chen, GH Lee, SY Chien… - Journal of the Chinese …, 2023 - Wiley Online Library
Abstract Four low‐spin {FeNO} 6 complexes,[Fe (NO)(PS2)(PS2H)](1, PS2H2= bis (2‐
dimercaptophenyl) phenylphosphine) with a pendant thiol,[Fe (NO)(PS2)(PS2CH3)](2) …
dimercaptophenyl) phenylphosphine) with a pendant thiol,[Fe (NO)(PS2)(PS2CH3)](2) …
Direct Reduction of NO to N2O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO}7 Complex
A Dey, T Albert, RY Kong, SN MacMillan… - Inorganic …, 2022 - ACS Publications
Addition of NO to a nonheme dithiolate-ligated iron (II) complex, FeII (Me3TACN)(S2SiMe2)(
1), results in the generation of N2O. Low-temperature spectroscopic studies reveal a …
1), results in the generation of N2O. Low-temperature spectroscopic studies reveal a …