Approximately one-half of all known protein crystal structures in the protein data bank (PDB)
contain metal ion cofactors, which play vital roles in charge neutralization, structure, and …

Copper is a bioessential element in biology with truly unique chemical characteristics in its
two relevant oxidation states+ I and+ II. Significant progress has been made in recent years …

Since their introduction in 1967, poly (pyrazolyl)-borates1 have found wide application in
coordination chemistry, and their complexes with most metals or metalloids of the periodic …

This book deals with polypyrazolylborates (scorpionates), a class of ligands known since
1966, but becoming rapidly popular with inorganic, organometallic and coordination …

Stability constants are fundamental to understanding the behavior of metal ions in aqueous
solution. Such understanding is important in a wide variety of areas, such as metal ions in …

The electron self-exchange rate constants of blue copper model complexes,[(−)-sparteine-N,
N '](maleonitriledithiolato-S, S ') copper ([Cu (SP)(mmt)]) 0/-, bis (2, 9-dimethy-1, 10 …

The type 1 (T1) or blue Cu (BC) proteins are a highly studied group of electron transfer (ET)
active sites in bioinorganic chemistry. In this review, we cover several more recent results …

A series of metal-varied [ML (SC6F5)] model complexes (where L= hydrotris (3, 5-
diisopropyl-1-pyrazolyl) borate and M= Mn, Fe, Co, Ni, Cu, and Zn) related to blue copper …

A series of metalloprotein mutants with novel copper cysteinate coordination environments
has been probed by resonance Raman (RR) spectroscopy. These include H117G, M121E …

Nitrous oxide reductase (N2OR) and cytochrome c oxidase (CcO) catalyze the reductions of
N2O to N2 during microbial denitrification and of O2 to H2O during cellular respiration …