Pincer complexes in photo-and electro-catalytic hydrogen evolution (HER) and carbon dioxide reduction reactions (CO2RR)

MAW Lawrence, C Thompson, SC Lorraine - Inorganica Chimica Acta, 2024 - Elsevier
Pincer complexes have aided in the understanding of a number of processes mediated by
transition metal compounds. In homogenous catalytic transformations, pincers as ligands …

N-heterocyclic carbene-ligated metal complexes and clusters for photocatalytic CO 2 reduction

Y Jiang, H Fei - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Photocatalytic reduction of CO2 to high value-added products is a green and sustainable
approach to reducing excessive CO2 emissions. N-heterocyclic carbenes (NHCs) are a …

Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid

K Kamada, J Jung, T Wakabayashi… - Journal of the …, 2020 - ACS Publications
A highly efficient tetradentate PNNP-type Ir photocatalyst, Mes-IrPCY2, was developed for
the reduction of carbon dioxide. The photocatalyst furnished formic acid (HCO2H) with 87 …

Combination of Organic Dye and Iron for CO2 Reduction with Pentanuclear Fe2Na3 Purpurin Photocatalysts

H Yuan, J Du, M Ming, Y Chen, L Jiang… - Journal of the American …, 2022 - ACS Publications
Molecular photocatalysts designed with earth-abundant elements are rare and challenging
in artificial photosynthesis study. Herein, we report a multimetallic Fe2Na3 purpurin (1) …

N-doped carbon dots-modulated interfacial charge transfer and surface structure in FeNbO4 photocatalysts for enhanced CO2 conversion selectivity to CH4

Y Cheng, S Jabeen, S Lei, N Liu, Y Liu, Y Liu… - Chemical Engineering …, 2024 - Elsevier
The photocatalytic carbon dioxide reduction reaction (CO 2 RR) is an innovative and reliable
technology to address the issues of energy shortage and climate change simultaneously …

Two-coordinate coinage metal complexes as solar photosensitizers

CN Muniz, CA Archer, JS Applebaum… - Journal of the …, 2023 - ACS Publications
Generating sustainable fuel from sunlight plays an important role in meeting the energy
demands of the modern age. Herein, we report two-coordinate carbene-metal-amide (cMa …

Self-Photosensitizing Dinuclear Ruthenium Catalyst for CO2 Reduction to CO

T Ishizuka, A Hosokawa, T Kawanishi… - Journal of the …, 2023 - ACS Publications
The promise of artificial photosynthesis to solve environmental and energy issues such as
global warming and the depletion of fossil fuels has inspired intensive research into …

Visible-Light-Driven Photocatalytic CO2 Reduction by Re(I) Photocatalysts with N-Heterocyclic Substituents

AV Müller, LA Faustino, KT de Oliveira… - ACS …, 2022 - ACS Publications
The properties and reactivity of metal complex photocatalysts for solar-to-fuel conversion
can be conveniently controlled by the molecular design of their ligands. In this work, rhenium …

Co-porphyrin/Ru-pincer complex coupled polymer with Z-scheme molecular junctions and dual single-atom sites for visible light-responsive CO2 reduction

S Chen, P Kong, H Niu, H Liu, X Wang, J Zhang… - Chemical Engineering …, 2022 - Elsevier
Covalent organic polymer has been considered as the promising organic semiconductor for
the photocatalytic CO 2 reduction reaction (CO 2 RR) due to its unique features such as …

Management of Triplet States in Modified Mononuclear Ruthenium (II) Complexes for Enhanced Photocatalysis

P Liang, Z Wang, S Hao, KK Chen, K Wu… - Angewandte …, 2024 - Wiley Online Library
Controlling the interplay between relaxation and charge/energy transfer processes in the
excited states of photocatalysts is crucial for the performance of artificial photosynthesis …