The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Illuminating the Black Box: A Perspective on Zeolite Crystallization in Inorganic Media

K Asselman, C Kirschhock… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Since the discovery of synthetic zeolites in the 1940s and their implementation
in major industrial processes involving adsorption, catalytic conversion, and ion exchange …

Hierarchical mesoporous zeolites: Direct self‐assembly synthesis in a conventional surfactant solution by kinetic control over the zeolite seed formation

Y Zhu, Z Hua, J Zhou, L Wang, J Zhao… - … A European Journal, 2011 - Wiley Online Library
By kinetic control over the zeolite seed formation, we report the direct fabrication of
hierarchical mesoporous zeolites using hexadecyl trimethyl ammonium bromide (CTAB) as …

A silica/PVA adhesive hybrid material with high transparency, thermostability and mechanical strength

H Pingan, J Mengjun, Z Yanyan, H Ling - RSC advances, 2017 - pubs.rsc.org
A cross-linked silica and polyvinyl alcohol (PVA) hybrid material was prepared via a sol–gel
process for use as a highly transparent, thermostable and mechanically strong coating. The …

Time-resolved dissolution elucidates the mechanism of zeolite MFI crystallization

KN Bozhilov, TT Le, Z Qin, T Terlier, A Palčić… - Science …, 2021 - science.org
Zeolite crystal growth mechanisms are not fully elucidated owing to their complexity wherein
the formation of a particular zeolite can occur by more than one crystallization pathway …

Predicting crystal growth via a unified kinetic three-dimensional partition model

MW Anderson, JT Gebbie-Rayet, AR Hill, N Farida… - Nature, 2017 - nature.com
Understanding and predicting crystal growth is fundamental to the control of functionality in
modern materials. Despite investigations for more than one hundred years,,,,, it is only …

Nucleation of Porous Crystals from Ion-Paired Prenucleation Clusters

N Pellens, N Doppelhammer… - Chemistry of …, 2022 - ACS Publications
Current nucleation models propose manifold options for the formation of crystalline
materials. Exploring and distinguishing between different crystallization pathways on the …

Methods for in situ spectroscopic probing of the synthesis of a zeolite

A Aerts, CEA Kirschhock, JA Martens - Chemical Society Reviews, 2010 - pubs.rsc.org
Unraveling the crystallization mechanism of zeolites remains an increasingly important
challenge in chemistry. During the last decade, in situ spectroscopic methods have provided …

A review of fine structures of nanoporous materials as evidenced by microscopic methods

Z Liu, N Fujita, K Miyasaka, L Han, SM Stevens… - …, 2013 - academic.oup.com
This paper reviews diverse capabilities offered by modern electron microscopy techniques
in studying fine structures of nanoporous crystals such as zeolites, silica mesoporous …

What can vibrational spectroscopy tell about the structure of dissolved sodium silicates?

I Halasz, M Agarwal, R Li, N Miller - Microporous and mesoporous …, 2010 - Elsevier
Aqueous solutions of various sodium silicates are frequent ingredients for the synthesis of
zeolites and mesoporous solids but their structure is poorly understood. This paper aims to …