The current status of MOF and COF applications
The amalgamation of different disciplines is at the heart of reticular chemistry and has
broadened the boundaries of chemistry by opening up an infinite space of chemical …
broadened the boundaries of chemistry by opening up an infinite space of chemical …
A historical overview of the activation and porosity of metal–organic frameworks
Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline,
porous materials has garnered increasing attention in a wide variety of applications such as …
porous materials has garnered increasing attention in a wide variety of applications such as …
Trace removal of benzene vapour using double-walled metal–dipyrazolate frameworks
In principle, porous physisorbents are attractive candidates for the removal of volatile
organic compounds such as benzene by virtue of their low energy for the capture and …
organic compounds such as benzene by virtue of their low energy for the capture and …
A ligand insertion mechanism for cooperative NH3 capture in metal–organic frameworks
Ammonia is a critical chemical in agriculture and industry that is produced on a massive
scale via the Haber–Bosch process. The environmental impact of this process, which uses …
scale via the Haber–Bosch process. The environmental impact of this process, which uses …
Covalent organic framework atropisomers with multiple gas-triggered structural flexibilities
Covalent organic frameworks (COFs) are emerging crystalline porous polymers, showing
great potential for applications but lacking gas-triggered flexibility. Atropisomerism was …
great potential for applications but lacking gas-triggered flexibility. Atropisomerism was …
[HTML][HTML] Materials for hydrogen-based energy storage–past, recent progress and future outlook
Globally, the accelerating use of renewable energy sources, enabled by increased
efficiencies and reduced costs, and driven by the need to mitigate the effects of climate …
efficiencies and reduced costs, and driven by the need to mitigate the effects of climate …
Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …
their ability to open and close their pores in an adaptive manner induced by chemical and …
Porous aromatic frameworks (PAFs)
Y Tian, G Zhu - Chemical reviews, 2020 - ACS Publications
Porous aromatic frameworks (PAFs) represent an important category of porous solids. PAFs
possess rigid frameworks and exceptionally high surface areas, and, uniquely, they are …
possess rigid frameworks and exceptionally high surface areas, and, uniquely, they are …
Machine learning the quantum-chemical properties of metal–organic frameworks for accelerated materials discovery
The modular nature of metal–organic frameworks (MOFs) enables synthetic control over
their physical and chemical properties, but it can be difficult to know which MOFs would be …
their physical and chemical properties, but it can be difficult to know which MOFs would be …
Porous metal-organic frameworks for gas storage and separation: Status and challenges
Gases are widely used as energy resources for industry and our daily life. Developing
energy cost efficient porous materials for gas storage and separation is of fundamentally and …
energy cost efficient porous materials for gas storage and separation is of fundamentally and …