The evolution of spiropyran: fundamentals and progress of an extraordinarily versatile photochrome

L Kortekaas, WR Browne - Chemical Society Reviews, 2019 - pubs.rsc.org
Spiropyrans have played a pivotal role in the emergence of the field of chromism following
their discovery in the early 20th century, with almost ubiquitous use in materials applications …

Hemithioindigo—an emerging photoswitch

S Wiedbrauk, H Dube - Tetrahedron Letters, 2015 - Elsevier
Hemithioindigo (HTI) is an emerging photoswitch with many advantageous properties
compared to the commonly used photoswitches like azobenzenes, spiropyranes, or …

[PDF][PDF] Modifying chemical landscapes by coupling to vacuum fields

JA Hutchison, T Schwartz, C Genet… - Angewandte Chemie …, 2012 - nano.isis.unistra.fr
Just as atoms exchange electrons to form molecular orbitals, an electromagnetic field can
interact with a quantum system by the exchange of photons. When this interaction is strong …

Mechanical reactivity of two different spiropyran mechanophores in polydimethylsiloxane

TA Kim, MJ Robb, JS Moore, SR White… - Macromolecules, 2018 - ACS Publications
We investigate the effect of pulling point location on the mechanochemical activation of two
isomers of spiropyran in cross-linked polymeric materials through computational …

Self-assembled Pd (II) barrels as containers for transient merocyanine form and reverse thermochromism of spiropyran

P Howlader, B Mondal, PC Purba… - Journal of the …, 2018 - ACS Publications
Self-assembly of a cis-blocked Pd (II) 90° ditopic acceptor [cis-(tmeda) Pd (NO3) 2](M) with a
tetradentate donor L 1 [benzene-1, 4-di (4-terpyridine)] in 2: 1 molar ratio yielded two …

Photoswitched DNA-binding of a photochromic spiropyran

J Andersson, S Li, P Lincoln… - Journal of the American …, 2008 - ACS Publications
The dramatically different DNA-binding properties of the two isomeric forms of a
photochromic spiropyran have been demonstrated, enabling photoswitched DNA binding …

Multidimensional electronic spectroscopy of photochemical reactions

P Nuernberger, S Ruetzel… - Angewandte Chemie …, 2015 - Wiley Online Library
Coherent multidimensional electronic spectroscopy can be employed to unravel various
channels in molecular chemical reactions. This approach is thus not limited to analysis of …

Ultrafast bidirectional photoswitching of a spiropyran

J Buback, M Kullmann, F Langhojer… - Journal of the …, 2010 - ACS Publications
We report on bidirectional photochemical switching of 6, 8-dinitro-1′, 3′, 3′-
trimethylspiro [2 H-1-benzopyran-2, 2′-indoline](6, 8-dinitro-BIPS) between the ring-closed …

Elucidating the mechanisms of acidochromic spiropyran-merocyanine interconversion

JTC Wojtyk, A Wasey, NN Xiao… - The Journal of …, 2007 - ACS Publications
The thermal and photochemical processes associated with the acid-induced conversions of
6-nitroBIPS, SP-1, to form the protonated merocyanine (MC− OH+) were investigated via …

Light-controlled molecular switches based on bistable spirocyclic organic and coordination compounds

VI Minkin - Russian Chemical Reviews, 2013 - iopscience.iop.org
Modern concepts of mechanisms of thermal and photochemical rearrangements responsible
for the photochromic properties of spiropyrans, spirooxazines, spiroperimidines and metal …