The chemistry of expanded porphyrins, which are higher homologues of porphyrins, has
been intensively explored for the last three decades. Expanded porphyrins exhibit …

Although the β-diketonato1 I and β-enaminoketonato2, 3 II ligands are among the most
ubiquitous chelating systems in coordination chemistry, the isoelectronic β-diketiminato …

Approximately one-half of all known protein crystal structures in the protein data bank (PDB)
contain metal ion cofactors, which play vital roles in charge neutralization, structure, and …

Among the transition metals, copper-based catalyst systems enable the widest range of N-
containing reagents in C–H amination to allow for the direct incorporation of versatile N …

The spectroscopic and electrochemical properties of blue copper proteins are strikingly
different from those of inorganic copper complexes in aqueous solution. Over three decades …

The electron self-exchange rate constants of blue copper model complexes,[(−)-sparteine-N,
N '](maleonitriledithiolato-S, S ') copper ([Cu (SP)(mmt)]) 0/-, bis (2, 9-dimethy-1, 10 …

The easily electronically and sterically tunable β-diketiminates are widely used auxiliary
ligands for the creation of a wide range of metal complexes with various oxidation states in …

β-Diketiminates are widely used supporting ligands for building a range of metal complexes
with different oxidation states, structures, and reactivities. This Perspective summarizes the …

Catalytic CÀH amination is an attractive strategy to prepare CÀN bonds without the need for
a pre-functionalized site.[1–3] This approach offers substantial opportunities to streamline …

Three-coordinate organometallic complexes are rare, especially with the prototypical methyl
ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron …