Recent catalytic routes for the preparation and the upgrading of biomass derived furfural and 5-hydroxymethylfurfural

C Xu, E Paone, D Rodríguez-Padrón… - Chemical Society …, 2020 - pubs.rsc.org
Furans represent one of the most important classes of intermediates in the conversion of non-
edible lignocellulosic biomass into bio-based chemicals and fuels. At present, bio-furan …

Catalytic self-transfer hydrogenolysis of lignin with endogenous hydrogen: road to the carbon-neutral future

X Shen, C Zhang, B Han, F Wang - Chemical Society Reviews, 2022 - pubs.rsc.org
Due to the depletion of fossil sources, it is imperative to develop a sustainable and carbon-
neutral biorefinery for supporting the fuel and chemical supply in modern society. Lignin, the …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Homogeneous and heterogeneous catalysts for hydrogenation of CO 2 to methanol under mild conditions

ST Bai, G De Smet, Y Liao, R Sun, C Zhou… - Chemical Society …, 2021 - pubs.rsc.org
In the context of a carbon neutral economy, catalytic CO2 hydrogenation to methanol is one
crucial technology for CO2 mitigation providing solutions for manufacturing future fuels …

First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Synergetic effect of Cu0− Cu+ derived from layered double hydroxides toward catalytic transfer hydrogenation reaction

Y Ren, Y Yang, L Chen, L Wang, Y Shi, P Yin… - Applied Catalysis B …, 2022 - Elsevier
As a safe and environmentally friendly selective hydrogenation method, catalytic transfer
hydrogenation (CTH) has aroused great interest in preparation of high-value-added …

Hydride transfer reactions catalyzed by cobalt complexes

W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

The golden age of transfer hydrogenation

D Wang, D Astruc - Chemical reviews, 2015 - ACS Publications
Hydrogenation is one of the most fundamental transformations in organic synthesis, and its
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …

Metal–ligand cooperation

JR Khusnutdinova, D Milstein - … Chemie International Edition, 2015 - Wiley Online Library
Metal–ligand cooperation (MLC) has become an important concept in catalysis by transition
metal complexes both in synthetic and biological systems. MLC implies that both the metal …

Stereodivergent catalysis

IP Beletskaya, C Najera, M Yus - Chemical reviews, 2018 - ACS Publications
This review covers diastereo-and enantiodivergent catalyzed reactions in acyclic and cyclic
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …