Abstract This Focus Review summarizes recent developments in palladium‐catalyzed
alkene carboalkoxylation and carboamination reactions. New synthetic methods that have …

The past decades in organic chemistry have witnessed significant improvements in synthetic
efficiency as a result of considerable progress in cascade reactions, tandem reactions, and …

A p-toluenesulfonic acid-catalyzed cascade reaction is reported for the synthesis of 4-
functionalized tetrahydrocarbazolones via the reaction of 4-(indol-2-yl)-4-oxobutanal …

The Pd-mediated cross-coupling of (hetero) arenes with alkenes may be an effective method
for the formation of a C–C bond from two C–H bonds. Discovered by Fujiwara and co …

Cascade reactions are step-economical processes for the synthesis of complex molecules
as they allow, in one step, the formation of multiple bonds. Over the last two decades …

In this minireview, we discuss some recently reported methods for the synthesis of polycyclic
heterocycles by palladium‐catalyzed double cyclization processes. Paradigmatic examples …

We report an unconventional I2-catalyzed cascade reaction for the synthesis of angular
triquinane derivatives with a fused heterocycle skeleton, leveraging enaminones and …

The combination of palladium catalysis and thermal cycloaddition is shown to transform
tricyclic aziridines into complex, stereodefined tetracyclic products in a single step. This …

Palladium‐catalyzed cascade cyclization received much attention in organic synthesis due
to its efficiency and rapid transformation of simple starting materials into complex molecular …

We report two ligand-controlled cascade reactions relying on the intramolecular
carbopalladation of skipped dienes. The use of a bulky monodentate phosphine ligand …