In this review article, we discuss advances in the chemistry of metal carbonyl clusters
(MCCs) spanning the last three decades, with an emphasis on the more recent reports and …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Iron nitrides are key intermediates in biological nitrogen fixation and the industrial Haber–
Bosch process, used to form ammonia from dinitrogen. However, the proposed successive …

We report the reactivity, structures and spectroscopic characterization of reactions of
phosphine-based ligands (mono-, di-and tri-dentate) with iron-carbide carbonyl clusters …

The deployment of metalloclusters in applications such as catalysis and materials synthesis
requires robust methods for site-differentiation: the conversion of clusters with symmetric …

Charged functional groups in the secondary coordination sphere (SCS) of a heterogeneous
nanoparticle or homogeneous electrocatalyst are of growing interest due to enhancements …

It is well-known that addition of a cationic functional group to a molecule lowers the
necessary applied potential for an electron transfer (ET) event. This report studies the effect …

Redox reactions, substitutions, and metalations are reported for the iron carbido sulfide
[Fe6C (CO) 14 (S)] 2–([1] 2–). Dianion [1] 2–oxidized to [Fe6C (CO) 16 (S)] 0 ([2] 0) upon …

DOE Catalysis Science Award DE-SC0018243 focused on the development and
mechanistic understanding of small-molecule-activation and catalysis by monomeric and …

The reduction of dinitrogen to ammonia is a critical transformation to modern society and is
responsible for much of the agricultural advancement over the past century. Industrially, this …