Molecular bismuth (III) monocations: structure, bonding, reactivity, and catalysis

C Lichtenberg - Chemical Communications, 2021 - pubs.rsc.org
Cationic bismuth (III) species [BiR2]+ with weakly coordinating counteranions feature two
monoanionic ligands R (such as aryls, amides, alcoholates or halides), a vacant bismuth …

[PDF][PDF] The bis (allyl) bismuth cation: a reagent for direct allyl transfer by Lewis acid activation and controlled radical polymerization

C Lichtenberg, F Pan, TP Spaniol, U Englert… - Angewandte Chemie …, 2012 - academia.edu
Cationic organometallic compounds of Group 3 (including the lanthanoids), 4, or 13
elements show increased Lewis acidity and electrophilicity compared to their neutral parent …

Main group metal lone-pair⋯ π (arene) interactions: a new bonding mode for supramolecular associations

I Caracelli, J Zukerman-Schpector, I Haiduc… - …, 2016 - pubs.rsc.org
Crystal structures of the heavier main group elements in low oxidation states have been
evaluated for the presence of supramolecular element (lp)⋯ π (arene) interactions that are …

Organic compounds of bismuth: synthesis, structure, and applications

VV Sharutin, AI Poddel'sky, OK Sharutina - Russian Journal of …, 2021 - Springer
The present review, describing the modern achievements in the area of synthetic methods,
investigation of specific structural features, and possibilities of practical use of the organic …

[PDF][PDF] Das Bis (allyl) bismut‐Kation: ein Reagens für direkte Allyl‐Übertragung und kontrollierte radikalische Polymerisation

C Lichtenberg, F Pan, TP Spaniol, U Englert… - Angewandte Chemie …, 2012 - academia.edu
Kationische metallorganische Komplexe der Elemente der Gruppen 3 (mit Lanthanoiden), 4
und 13 zeigen eine hçhere Lewis-Acidität und Elektrophilie als die neutralen …

[PDF][PDF] Homoleptic organometallic compounds of heavy pnicogens. Crystal and molecular structure of [2-(iPr2NCH2) C6H4] 3M (M= Sb, Bi)

I Chirca, A Soran, A Silvestru, C Silvestru - Rev. Roum. Chim, 2015 - revroum.lew.ro
Two new homoleptic triorganopnicogen (III) species,[2-(iPr2NCH2) C6H4] 3M [M= Sb (2), Bi
(3)] were obtained by reacting [2-(iPr2NCH2) C6H4] MgBr (prepared in situ from [2 …

Synthesis and Structure of Organobismuth Chlorides and Triflates Containing (C, E)‐Chelating Ligands (E= O, S) and Their Catalytic Application in the Allylation of …

N Tan, Y Chen, Y Zhou, CT Au, SF Yin - ChemPlusChem, 2013 - Wiley Online Library
Four air‐stable hypervalent organobismuth compounds with (C, O)‐or (C, S)‐chelating
ligands, namely, R2BiCl (R= 2‐(MeECH2) C6H4; E= O (3), S (4)),[2‐(MeOCH2) C6H4] …

Organoantimony (III) and-bismuth (III) hypervalent pseudohalides. An experimental and theoretical study

A Toma, CI Raţ, A Silvestru, T Rueffer, H Lang… - Journal of …, 2013 - Elsevier
The reaction between the organopnicogen (III) chlorides R 2 MCl and RMCl 2 [M= Sb, Bi; R=
2-(Me 2 NCH 2) C 6 H 4] and alkali metal pseudohalides in a 1: 1 and a 1: 2 molar ratio …

Синтез и строение 2-фенилкарборанилкарбоксилата дифенилвисмута

ВИ Брегадзе, СА Глазун, АН Ефремов… - Вестник Южно …, 2020 - cyberleninka.ru
Взаимодействием трифенилвисмута и 2-фенилкарборанилкарбоновой кислоты (1: 1
мольн.) в бензоле получен с выходом 91% 2-фенилкарборанилкарбоксилат …

Crystal structure of 6-cyclohexyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl nitrate, C20H23O3N2Bi

N Tan, S Wu, Y Huiqiong, D Lan, CT Au… - … für Kristallographie-New …, 2019 - degruyter.com
Crystal structure of 6-cyclohexyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl nitrate,
C20H23O3N2Bi Skip to content Should you have institutional access? Here's how to get it ... De …