Ordered anion adlayers on metal electrode surfaces

OM Magnussen - Chemical reviews, 2002 - ACS Publications
In this paper the structure and phase behavior of anion adlayers at the metal-electrolyte
interface and their influence on the metal substrate structure and on electrochemical …

In situ scanning tunneling microscopy in electrolyte solutions

K Itaya - Progress in Surface Science, 1998 - Elsevier
Until recently, there had been only few in situ methods available for the structural
determination of an electrode surface in solution at the atomic level. Now, several recent …

How cations affect the electric double layer and the rates and selectivity of electrocatalytic processes

MM Waegele, CM Gunathunge, J Li, X Li - The Journal of chemical …, 2019 - pubs.aip.org
Electrocatalysis is central to the production of renewable fuels and high-value commodity
chemicals. The electrolyte and the electrode together determine the catalytic properties of …

“Beyond adsorption” descriptors in hydrogen electrocatalysis

L Rebollar, S Intikhab, NJ Oliveira, Y Yan, B Xu… - ACS …, 2020 - ACS Publications
Although electrochemical hydrogen evolution and oxidation are arguably the best-
understood reactions in electrocatalysis, the anomalous effect of pH on hydrogen reaction …

Essential role of lattice oxygen in methanol electrochemical refinery toward formate

F Meng, Q Wu, K Elouarzaki, S Luo, Y Sun, C Dai… - Science …, 2023 - science.org
Developing technologies based on the concept of methanol electrochemical refinery (e-
refinery) is promising for carbon-neutral chemical manufacturing. However, a lack of …

Enhanced electrocatalysis of the oxygen reduction reaction based on patterning of platinum surfaces with cyanide

D Strmcnik, M Escudero-Escribano, K Kodama… - Nature …, 2010 - nature.com
The slow rate of the oxygen reduction reaction in the phosphoric acid fuel cell is the main
factor limiting its wide application. Here, we present an approach that can be used for the …

Electrochemical Applications of in Situ Scanning Probe Microscopy

AA Gewirth, BK Niece - Chemical reviews, 1997 - ACS Publications
The application of the scanning tunneling microscope (STM) and the atomic force
microscope (AFM) to structural problems at the electrified solid-liquid interface is one of the …

pH and alkali cation effects on the Pt cyclic voltammogram explained using density functional theory

IT McCrum, MJ Janik - The Journal of Physical Chemistry C, 2016 - ACS Publications
Platinum electrode cyclic voltammograms show features at low potentials which correspond
to adsorption/desorption processes on Pt (111), Pt (100), and Pt (110) facets that have …

At least three contiguous atoms are necessary for CO formation during methanol electrooxidation on platinum

A Cuesta - Journal of the American Chemical Society, 2006 - ACS Publications
We have used cyanide-modified Pt (111) electrodes to investigate the size and geometry of
the minimum atomic ensemble necessary for the oxidation of methanol on Pt electrodes …

Scanning probe microscopy for electrocatalysis

Y Wang, SA Skaanvik, X Xiong, S Wang, M Dong - Matter, 2021 - cell.com
The development of high-efficiency energy storage and conversion devices requires a
deeper understanding of the structure-activity relationship of electrocatalysts, material …