Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts

GC Vougioukalakis, RH Grubbs - Chemical reviews, 2010 - ACS Publications
The fascinating story of olefin (or alkene) metathesis (eq 1) began almost five decades ago,
when Anderson and Merckling reported the first carbonrcarbon double-bond rearrangement …

The Development of L2X2RuCHR Olefin Metathesis Catalysts:  An Organometallic Success Story

TM Trnka, RH Grubbs - Accounts of Chemical Research, 2001 - ACS Publications
In recent years, the olefin metathesis reaction has attracted widespread attention as a
versatile carbon− carbon bond-forming method. Many new applications have become …

Molybdenum and tungsten imido alkylidene complexes as efficient olefin‐metathesis catalysts

RR Schrock, AH Hoveyda - Angewandte Chemie International …, 2003 - Wiley Online Library
Catalytic olefin metathesis has quickly emerged as one of the most often‐used
transformations in modern chemical synthesis. One class of catalysts that has led the way to …

Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins

RR Schrock, JS Murdzek, GC Bazan… - Journal of the …, 1990 - ACS Publications
The reaction between Mo (CZ-Bu)(dme) Cl3 (dme= 1, 2-dimethoxyethane) and Me3SiNHAr
(Ar= 2, 6-diisopropyl phenyl) yields Mo (CZ-Bu)(NHAr) Cl2 (dme)(1), which upon treatment …

The metathesis reactions: from a historical perspective to recent developments

D Astruc - New Journal of Chemistry, 2005 - pubs.rsc.org
Metathesis is one of the most spectacular recent improvements in synthetic strategies for
organic synthesis and polymer science. The historical aspects and modern developments of …

Polymer synthesis and organotransition metal chemistry

RH Grubbs, W Tumas - Science, 1989 - science.org
Mechanistic and synthetic studies in organometallic chemistry have provided considerable
insight into olefin metathesis and Ziegler-Natta polymerization. New homogeneous olefin …

Silasesquioxanes as ligands in inorganic and organometallic chemistry

FJ Feher, TA Budzichowski - Polyhedron, 1995 - Elsevier
Silasesquioxanes are an interesting class of ligands for both main group and transition-
metal elements. A variety of coordination environments can be supported by …

Preparation and reactivity of several alkylidene complexes of the type W (CHR')(N-2, 6-C6H3-iso-Pr2)(OR) 2 and related tungstacyclobutane complexes. Controlling …

RR Schrock, RT DePue, J Feldman… - Journal of the …, 1988 - ACS Publications
The emission properties of jet-cooled adducts between ethers and some aromatic
hydrocarbons may be accounted for by as-suming an excited state that is a superposition of …

[图书][B] Carbene chemistry: from fleeting intermediates to powerful reagents

G Bertrand - 2002 - api.taylorfrancis.com
Carbene Chemistry Page 1 Page 2 Carbene Chemistry FROM FLEETING
INTERMEDIATES TO POWERFUL REAGENTS Edited by Guy Bertrand Page 3 ISBN 0-203-91092-3 …

Recent advances in the chemistry of d alkylidene and metallacycobutane complexes

J Feldman, RR Schrock - Progress in inorganic chemistry, 1991 - books.google.com
The first alkylidene complex in which the metal can be said to have a d0 electron
configuration (counting the alkylidene ligand as a dianion) was discovered in 1974 (1) …