Epoxy thermosets designed for chemical recycling

T Türel, Ö Dağlar, F Eisenreich… - Chemistry–An Asian …, 2023 - Wiley Online Library
Epoxy thermosets constitute a significant portion of high‐performance plastics, as they
possess excellent thermal and mechanical properties that are applicable in a wide range of …

Design for disassembly of composites and thermoset by using cleavable ionic liquid monomers as molecular building blocks

G Perli, CY Okada, C Michelin, Y El Omari… - Composites Part B …, 2023 - Elsevier
Aircraft, automotive industries and the increasing numbers of wind turbine blade lead to a
huge amount of carbon fiber reinforced polymers requiring to be recycled and/or reused in a …

Preparation and Performances of Degradable Polybenzoxazine by Ring-Opening Metathesis Polymerization

W Wang, J Jiang, Q An, R Shi, S Shao… - ACS Sustainable …, 2023 - ACS Publications
Due to its outstanding properties, benzoxazine resin is widely used in the manufacturing of
machinery, aerospace, and electrical products. However, once polybenzoxazine and its …

Theoretical Analysis of Physical and Chemical CO2 Absorption by Tri- and Tetraepoxidized Imidazolium Ionic Liquids

L Wylie, G Perli, J Avila, S Livi… - The Journal of …, 2022 - ACS Publications
The efficient capture of CO2 from flue gas or directly from the atmosphere is a key subject to
mitigate global warming, with several chemical and physical absorption methods previously …

Intercalation of ionic liquids into LDH structures for microwave-accelerated polymerizations

H Beneš, M Konefał, S Bujok, O Mrózek… - Inorganic …, 2023 - ACS Publications
Microwave-accelerated ring-opening polymerization (ROP) of cyclic esters catalyzed by
ionic liquid (IL) anions, intercalated into layered double hydroxides (LDHs), has been …

Solvent Dependency of Catalyst‐Substrate Aggregation Through ππ Stacking in Photoredox Catalysis

L Wylie, JP Barham, B Kirchner - ChemPhysChem, 2023 - Wiley Online Library
Assemblies of photoredox catalysts and their target substrates prior to photoexcitation is a
phenomenon naïvely overlooked by the majority of synthetic chemists, but can have …

Preparation of environmentally friendly ionic liquids-toughened polylactic acid/nanofibrillated cellulose composites with high strength and precipitation resistance

Z Zhang, S Qian, X Li, C Zhu, Z Li - Chemical Engineering Journal, 2024 - Elsevier
Polylactic acid (PLA) is one of the most promising biodegradable materials, but poor
toughness severely limits its application. Ionic liquids (ILs) have excellent plasticizing effects …

Novel Aphid-Repellent Fiber Mats Based on Poly (lactic acid)-Containing Ionic Liquids

C Merlini, V Lacotte, VO Castro, G Perli, P da Silva… - ACS …, 2024 - ACS Publications
To protect crops as well as human and animal health, the development of novel repellents
based on biopolymers is critical for a growing world population. Here, novel aphid-repellent …

Thermodynamics of Tri- and Tetraepoxyimidazolium NTf2 Amine Polyaddition: A Theoretical Perspective

L Wylie, G Perli, J Duchet-Rumeau, S Livi… - The Journal of …, 2023 - ACS Publications
The thermodynamics of newly designed tri-and tetraepoxyimidazolium NTf2 monomers
reacting with several diamines used as curing agents to form epoxy/amine thermosets was …

Epoxidized Ionic Liquids as Processing Auxiliaries of Poly (Lactic Acid) Matrix: Influence on the Manufacture, Structural and Physical Properties

C Merlini, V Oliveira Castro, G Perli, Y El Omari, S Livi - Nanomaterials, 2023 - mdpi.com
In this study, we set out to modify poly (lactic acid)(PLA) by incorporating epoxidized ionic
liquids (ILs) that were specifically designed with imidazolium-NTf2 moieties. First, we …