Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal …

TR Cook, YR Zheng, PJ Stang - Chemical reviews, 2013 - ACS Publications
In 1893, Alfred Werner described the structure of octahedral transition metal complexes and
provided the basis for assigning coordination number and oxidation state to what were then …

Highlights on contemporary recognition and sensing of fluoride anion in solution and in the solid state

M Cametti, K Rissanen - Chemical Society Reviews, 2013 - pubs.rsc.org
The fluoride anion has recently gained well deserved attention among the scientific
community for its importance in many fields of human activities, but also for concerns on its …

Low-Dimensional Metal–Organic Magnets as a Route toward the S = 2 Haldane Phase

J Pitcairn, A Iliceto, L Cañadillas-Delgado… - Journal of the …, 2023 - ACS Publications
Metal–organic magnets (MOMs), modular magnetic materials where metal atoms are
connected by organic linkers, are promising candidates for next-generation quantum …

An overlooked yet ubiquitous fluoride congenitor: binding bifluoride in triazolophanes using computer-aided design

RO Ramabhadran, Y Liu, Y Hua, M Ciardi… - Journal of the …, 2014 - ACS Publications
Despite its ubiquity during the binding and sensing of fluoride, the role of bifluoride (HF2–)
and its binding properties are almost always overlooked. Here, we give one of the first …

Magnetic order in quasi-two-dimensional molecular magnets investigated with muon-spin relaxation

AJ Steele, T Lancaster, SJ Blundell, PJ Baker… - Physical Review B …, 2011 - APS
We present the results of a muon-spin relaxation (μ+ SR) investigation into magnetic
ordering in several families of layered quasi-two-dimensional molecular antiferromagnets …

Ligand field design enables quantum manipulation of spins in Ni 2+ complexes

MK Wojnar, K Kundu, A Kairalapova, X Wang… - Chemical …, 2024 - pubs.rsc.org
Creating the next generation of quantum systems requires control and tunability, which are
key features of molecules. To design these systems, one must consider the ground-state and …

A survey of interactions in crystal structures of pyrazine-based compounds

F Taghipour, M Mirzaei - Acta Crystallographica Section C …, 2019 - journals.iucr.org
The important role of pyrazine (pz) and its derivatives in fields such as biochemistry and
pharmacology, as well as in the study of magnetic properties, is surveyed. Recognition of …

Enhancing easy-plane anisotropy in bespoke Ni (II) quantum magnets

JL Manson, ZE Manson, A Sargent, DY Villa, NL Etten… - Polyhedron, 2020 - Elsevier
We examine the crystal structures and magnetic properties of several S= 1 Ni (II)
coordination compounds, molecules and polymers, that include the bridging ligands HF 2 …

Quasi-2D Heisenberg Antiferromagnets [CuX(pyz)2](BF4) with X = Cl and Br

M Kubus, A Lanza, R Scatena… - Inorganic …, 2018 - ACS Publications
Two Cu2+ coordination polymers [CuCl (pyz) 2](BF4) 1 and [CuBr (pyz) 2](BF4) 2 (pyz=
pyrazine) were synthesized in the family of quasi two-dimensional (2D)[Cu (pyz) 2] 2+ …

Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an quantum antiferromagnet

J Brambleby, JL Manson, PA Goddard, MB Stone… - Physical Review B, 2017 - APS
The magnetic ground state of the quasi-one-dimensional spin-1 antiferromagnetic chain is
sensitive to the relative sizes of the single-ion anisotropy (D) and the intrachain (J) and …