Advances in synthetic applications of hypervalent iodine compounds

A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Transition-metal-free coupling reactions

CL Sun, ZJ Shi - Chemical reviews, 2014 - ACS Publications
Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Comparison of oxidative aromatic coupling and the Scholl reaction

M Grzybowski, K Skonieczny… - Angewandte Chemie …, 2013 - Wiley Online Library
Does the dehydrogenative coupling of aromatic compounds mediated by AlCl3 at high
temperatures and also by FeCl3, MoCl5, PIFA, or K3 [Fe (CN) 6] at room temperature …

Aryl− aryl bond formation one century after the discovery of the Ullmann reaction

J Hassan, M Sévignon, C Gozzi, E Schulz… - Chemical …, 2002 - ACS Publications
Arylraryl bond formation is one of the most important tools of modern organic synthesis.
These bonds are very often found in natural products such as alkaloids as well as in …

Recent developments in the chemistry of polyvalent iodine compounds

VV Zhdankin, PJ Stang - Chemical reviews, 2002 - ACS Publications
The organic chemistry of polyvalent iodine compounds has experienced an unprecedented,
explosive development during the last decade of the 20th century. A quick SciFinder Scholar …

Hypervalent iodine-mediated phenol dearomatization in natural product synthesis

L Pouységu, D Deffieux, S Quideau - Tetrahedron, 2010 - Elsevier
The richness of the chemistry of phenols is quite remarkable when one realizes that it is
simply the presence of a hydroxy group on a benzene ring that renders this otherwise quasi …

Intermolecular oxidative cross-coupling of arenes

JA Ashenhurst - Chemical Society Reviews, 2010 - pubs.rsc.org
Biaryls constitute an important subunit found in medicinal agents, functional materials, and
natural products. While the Suzuki reaction and related processes currently represent the …

Hypervalent iodine reagents as a new entrance to organocatalysts

T Dohi, Y Kita - Chemical communications, 2009 - pubs.rsc.org
The catalytic utilization of hypervalent iodine reagents, largely in consideration of
economical and environmental viewpoints, is a most attractive strategy due to their unique …

Hypervalent iodine reactions utilized in carbon–carbon bond formations

IFD Hyatt, L Dave, N David, K Kaur… - Organic & …, 2019 - pubs.rsc.org
Advances in hypervalent iodine chemistry have put the field on the precipice of a second
golden age; the first being pioneered in the 1990s. During that period, C–C bond forming …

Fluoroalcohols: versatile solvents in hypervalent iodine chemistry and syntheses of diaryliodonium (III) salts

T Dohi, N Yamaoka, Y Kita - Tetrahedron, 2010 - Elsevier
We first introduced 1, 1, 1, 3, 3, 3-hexafluoroisopropanol (HFIP) and 2, 2, 2-trifluoroethanol
(TFE) as unique solvents for reactions involving hypervalent iodine-mediated phenolic …