Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications

G Chakraborty, IH Park, R Medishetty… - Chemical Reviews, 2021 - ACS Publications
Among the recent developments in metal-organic frameworks (MOFs), porous layered
coordination polymers (CPs) have garnered attention due to their modular nature and …

Photoreactive crystals exhibiting [2+ 2] photocycloaddition reaction and dynamic effects

BB Rath, JJ Vittal - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Conducting a reaction in the solid state eliminates the usage of solvents. If such
reactions are conducted in a single-crystal to single-crystal (SCSC) fashion, then structural …

Control of interpenetration and structural transformations in the interpenetrated MOFs

M Gupta, JJ Vittal - Coordination Chemistry Reviews, 2021 - Elsevier
Interpenetration is an intriguing phenomenon in metal–organic framework (MOF) structures
and considered as one of the framework isomers or supramolecular isomers. This has …

Diastereoselective guest-shape dependent [2+ 2]-photodimerization of 2-cyclopenten-1-one trapped within a metal–organic framework

PA Demakov, DN Dybtsev, VP Fedin - Chemical Communications, 2023 - pubs.rsc.org
UV-induced [2+ 2] dimerization of 2-cyclopenten-1-one and 2-methyl-2-cyclopenten-1-one
was successfully carried out in a single-crystal-to-single-crystal manner within a porous …

Construction of Photoreactive Chiral Metal–Organic Frameworks and Their [2+ 2] Photocycloaddition Reactions

S Kim, J An, H Choi, SH Jung, SS Lee… - Inorganic Chemistry, 2023 - ACS Publications
Chiral metal–organic frameworks (CMOFs) and solid-state [2+ 2] photocyclization have been
explored as independent areas in crystal engineering. We herein report the photoreactive …

Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond

Q Zhang, Y Wang, P Braunstein, JP Lang - Chemical Society Reviews, 2024 - pubs.rsc.org
Olefin [2+ 2] photocycloaddition reactions based on coordination-bond templates provide
numerous advantages for the selective synthesis of cyclobutane compounds. This review …

A study of GUPT-2, a water-stable zinc-based metal–organic framework as a highly selective and sensitive fluorescent sensor in the detection of Al 3+ and Fe 3+ ions

ST Wang, X Zheng, SH Zhang, G Li, Y Xiao - CrystEngComm, 2021 - pubs.rsc.org
A novel luminescent Zn (II)-based metal–organic framework with twofold interpenetrating [Zn
(DHT)(BPP)] n (GUPT-2){GUPT= Guangdong University of Petrochemical Technology …

Chemo-and stereoselective intermolecular [2+ 2] photocycloaddition of conjugated dienes using colloidal nanocrystal photocatalysts

Y Jiang, M Yang, Y Wu, R López-Arteaga, CR Rogers… - Chem catalysis, 2021 - cell.com
The use of visible-light photosensitizers to power [2+ 2] photocycloadditions that produce
complex tetrasubstituted cyclobutanes is a true success of photochemistry, but the scope of …

[HTML][HTML] [2+ 2] Photocycloaddition Reaction as A Tool to Monitor the Molecular Motions in the Solid State by Mechanochemical Grinding

JJ Vittal - Journal of Photochemistry and Photobiology C …, 2023 - Elsevier
Mechanochemistry, a burgeoning field in green chemistry, has been utilized frequently to
synthesize various organic molecules, metal complexes, coordination polymers (CPs) and …

Sequential Solid‐State Transformations Involving Consecutive Rearrangements of Secondary Building Units in a Metal–Organic Framework (MOF)

F Dai, X Wang, Y Wang, Z Liu… - Angewandte Chemie …, 2020 - Wiley Online Library
Solid‐state transformations in metal–organic frameworks (MOFs) are important and have led
to the creation of new MOF structures. Solid‐state transformations from interpenetrated to …