Metal complexes of corrole
S Nardis, F Mandoj, M Stefanelli, R Paolesse - Coordination Chemistry …, 2019 - Elsevier
The coordination chemistry of corrole is one of the most intriguing aspects of this contracted
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …
Seven clues to ligand noninnocence: the metallocorrole paradigm
Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
Synthesis, Spectral, Redox, and Sensing Studies of β-Dicyanovinyl-Appended Corroles and Their Metal Complexes
A new family of β-dicyanovinyl (DCV)-appended corroles represented as MTPC (MN)(where
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
Hypercorroles Formed via the Tail that Wagged the Dog: Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents
WR Osterloh, N Desbois, CP Gros… - Inorganic Chemistry, 2022 - ACS Publications
A series of cobalt nitrophenylcorroles were spectrally characterized in CH2Cl2, and under
certain solution conditions, several compounds were shown to exhibit hypercorrole spectra …
certain solution conditions, several compounds were shown to exhibit hypercorrole spectra …
Panchromatic and Perturbed Absorption Spectral Features and Multiredox Properties of Dicyanovinyl-and Dicyanobutadienyl-Appended Cobalt Corroles
Four new β-functionalized π-extended cobalt corroles with one and two dicyanovinyl (DCV)
or dicyanobutadienyl (DCBD) moieties at the 3-and 3, 17-positions have been synthesized …
or dicyanobutadienyl (DCBD) moieties at the 3-and 3, 17-positions have been synthesized …
Catalytic Four-Electron Reduction of Oxygen to Water by a Molecular Cobalt Complex Consisting of a Proton Exchanging Site at the Secondary Coordination Sphere
Controlling the selectivity of 4e–/4H+ reduction of oxygen over 2e–/2H+ reduction is a key
challenge in making efficient catalysts for fuel cell cathodes. A tyrosine residue poised over …
challenge in making efficient catalysts for fuel cell cathodes. A tyrosine residue poised over …
Altering the Site of Electron Abstraction in Cobalt Corroles via meso-Trifluoromethyl Substituents
WR Osterloh, N Desbois, P Fleurat-Lessard… - Inorganic …, 2023 - ACS Publications
A mono-DMSO cobalt meso-CF3 corrole, formulated as (CF3) 3CorCo (DMSO), where (CF3)
3Cor is the trianion of 5, 10, 15-tris (trifluoromethyl) corrole, was synthesized and …
3Cor is the trianion of 5, 10, 15-tris (trifluoromethyl) corrole, was synthesized and …
Cobalt corroles as electrocatalysts for water oxidation: Strong effect of substituents on catalytic activity
Two Co (III) complexes (1Py 2 and 2Py 2) of new corrole ligands H 3 L1 (5, 15-bis (p-
methylcarboxyphenyl)-10-(o-methylcarboxyphenyl) corrole) and H 3 L2 (5, 15-bis (p …
methylcarboxyphenyl)-10-(o-methylcarboxyphenyl) corrole) and H 3 L2 (5, 15-bis (p …
A DMRG/CASPT2 investigation of metallocorroles: quantifying ligand noninnocence in archetypal 3d and 4d element derivatives
Hybrid density functional theory (B3LYP) and density matrix renormalization group (DMRG)
theory have been used to quantitatively compare the degree of ligand noninnocence …
theory have been used to quantitatively compare the degree of ligand noninnocence …