Soft-mechanochemistry: mechanochemistry inspired by nature

P Lavalle, F Boulmedais, P Schaaf, L Jierry - Langmuir, 2016 - ACS Publications
Cells and bacteria use mechanotransduction processes to transform a mechanical force into
a chemical/biochemical response. The area of chemistry where chemical reactions are …

Thin film nanoarchitectonics

K Ariga, Q Ji, W Nakanishi, JP Hill - Journal of Inorganic and …, 2015 - Springer
A paradigm shift from nanotechnology to nanoarchitectonics is necessary. Individual nano-
objects are required to be constructed into functional nanoarchitectures in order to develop …

Bioinspired nanoarchitectonics as emerging drug delivery systems

K Ariga, K Kawakami, M Ebara… - New Journal of …, 2014 - pubs.rsc.org
We propose an important paradigm shift in the preparation of functional materials with well-
designed nanostructures, from the nanotechnological to the nanoarchitectonic approach …

A guide to design functional molecular liquids with tailorable properties using pyrene-fluorescence as a probe

F Lu, T Takaya, K Iwata, I Kawamura, A Saeki, M Ishii… - Scientific Reports, 2017 - nature.com
Abstract Solvent-free, nonvolatile, room-temperature alkylated-π functional molecular liquids
(FMLs) are rapidly emerging as a new generation of fluid matter. However, precision design …

Monitoring fluorescence response of amphiphilic flapping molecules in compressed monolayers at the air–water interface

W Nakanishi, S Saito, N Sakamoto… - Chemistry–An Asian …, 2019 - Wiley Online Library
The air–water interface, which is the boundary of two phases with a large difference in
polarity, gives a distinct environment compared with bulk water or air. Since the interface …

Dynamic control of intramolecular rotation by tuning the surrounding two-dimensional matrix field

T Mori, H Chin, K Kawashima, HT Ngo, NJ Cho… - ACS …, 2019 - ACS Publications
The intramolecular rotation of 4-farnesyloxyphenyl-4, 4-difluoro-4-bora-3a, 4a-diaza-s-
indacene (BODIPY-ISO) was controlled by tuning its local physical environment within a …

Mechanically induced opening–closing action of binaphthyl molecular pliers: digital phase transition versus continuous conformational change

T Mori, D Ishikawa, Y Yonamine, Y Fujii… - …, 2017 - Wiley Online Library
Reversible dynamic control of structure is a significant challenge in molecular
nanotechnology. Previously, we have reported a mechanically induced continuous (analog) …

Helicity manipulation of a double-paddled binaphthyl in a two-dimensional matrix field at the air–water interface

M Ishii, T Mori, W Nakanishi, JP Hill, H Sakai, K Ariga - ACS nano, 2020 - ACS Publications
Molecular behavior and functionality are affected by their prevailing immediate environment.
Molecular machines function according to conformational variations and have been studied …

Molecular rotors confined at an ordered 2D interface

T Mori, H Komatsu, N Sakamoto, K Suzuki… - Physical Chemistry …, 2018 - pubs.rsc.org
Intramolecular rotation of molecules contained in a two-dimensional monolayer or a three-
dimensional collapsed film at an air–water interface was investigated by in situ fluorescence …

Ultra-confined controllable cyclic peptides as supramolecular biomaterials

MS Chorsi, W Linthicum, A Pozhidaeva, C Mundrane… - Nano Today, 2024 - Elsevier
The capacity to design molecules capable of orchestrated movements in response to
specific stimuli could yield functional biomaterials suitable for diverse innovative materials …