Precisely tailoring heterometallic polyoxotitanium clusters for the efficient and selective photocatalytic oxidation of hydrocarbons

MY Gao, H Bai, X Cui, S Liu, S Ling, T Kong… - Angewandte …, 2022 - Wiley Online Library
Photocatalysis is a promising yet challenging approach for the selective oxidation of
hydrocarbons to valuable oxygenated chemicals with O2 under mild conditions. In this work …

Synthesis of Technetium Carboxylates: Wheel-Like Octanuclear Clusters (Tc8(μ-O)8(RCOO)16, Where R = CF3, C6H5)─Potential Nanobuilding Units for Tc …

MA Volkov, EV Abkhalimov, AP Novikov… - Inorganic …, 2024 - ACS Publications
Herein, we studied the behavior of TcO4–in trifluoroacetic anhydride (TFAA) under visible
light irradiation in situ by UV–vis spectroscopy. One carboxylate of Tc (VII) C2F3O5Tc (1) …