Fine-branching structure in high-pressure, low-density polyethylenes by 50.10-MHz carbon-13 NMR analysis

T Usami, S Takayama - Macromolecules, 1984 - ACS Publications
The fine-branchingstructures in high-pressure, low-density polyethylenes (HP-LDPEs) have
been studied by 50.10-MHz 13C NMR analysis. When the 13C NMR spectra of some HP …

Identification of branches in low-density polyethylenes by Fourier transform infrared spectroscopy

T Usami, S Takayama - Polymer journal, 1984 - nature.com
Qualitative and quantitative analysis of short chain branches was carried out on a series of
low-density polyethylenes by Fourier transform infrared spectroscopy. The peak position of …

Branching in low density polyethylene by 13C-NMR

DC Bugada, A Rudin - European polymer journal, 1987 - Elsevier
An optimized experimental procedure has been developed for the 13 C-NMR analysis of
polyethylenes. These analyses were performed at 62.5 MHz in 60–80 (w/w)% mixtures in …

Intramolecular hydrogen transfers in vinyl chloride polymerization: routes to doubly branched structures and internal double bonds

WH Starnes, VG Zaikov, HT Chung… - …, 1998 - ACS Publications
During the preparation of poly (vinyl chloride)(PVC) under low monomer pressures,
intramolecular hydrogen transfers (“backbites”) lead to the formation of small amounts of 1, 3 …

Solvent effect on the morphology of poly (oxy-1, 4-benzenediylcarbonyl) whiskers from p-acetoxybenzoic acid

K Kimura, S Endo, Y Kato, Y Yamashita - Polymer, 1994 - Elsevier
Abstract Poly (oxy-1, 4-benzenediylcarbonyl)(POB) whiskers from p-acetoxybenzoic acid
were prepared in mixtures of liquid paraffin having many branched carbons (LP) and …

Determination of short-chain branching up to C6 in low-density polyethylenes by high-resolution pyrolysis-hydrogenation gas chromatography

H Ohtani, S Tsuge, T Usami - Macromolecules, 1984 - ACS Publications
Short-chain branching upto hexyl in low-density polyethylenes (LDPE) has been studied by
pyrolysis-hydrogenation fused-silica capillary gas chromatography. The branch content was …

13C NMR microstructure determinations of low‐density polyethylene homopolymers and copolymers

JC Randall, CJ Ruff… - Recueil des Travaux …, 1991 - Wiley Online Library
Low‐density polyethylenes, prepared by free radical processes in high‐pressure reactors,
are dendritic polymers with complex microstructures. Both long‐and short‐chain aliphatic …

The catalytic degradation reaction of polypropylene with silica-alumina.

Y Ishihara, H Nanbu, C Iwata, T Ikemura… - Bulletin of the Chemical …, 1989 - jlc.jst.go.jp
A detailed analysis was carried out on the catalytic degradation of polypropylene with silica–
alumina, using a glass tube reactor (25φ× 150 mm) at 180 to 300° C and a N 2 flow rate of …

Investigations of the thermodegradation of ethylene–α-olefin copolymers by pyrolysis-gas chromatography (Py-GC)

S Duc, N Lopez - Polymer, 1999 - Elsevier
The thermodegradation of several ethylene–α-olefin copolymers, where α-olefin was butene-
1, hexene-1, octene-1 or 4-methyl-1-pentene, was investigated by the pyrolysis-gas …

Solution NMR of synthetic polymers

A Bunn - Special Applications, 1993 - Springer
Solution NMR of Synthetic Polymers Page 1 Solution NMR of Synthetic Polymers A. Bunn rCI pic,
Wilton Materials Research Centre. PO Box No. 90, Wilton, Middlesbrough, Cleveland, TS6 81£ …