Imine-and amine-type macrocycles derived from chiral diamines and aromatic dialdehydes

J Lisowski - Molecules, 2022 - mdpi.com
The condensation of aromatic dialdehydes with chiral diamines, such as 1, 2-trans-
diaminocyclohexane, leads to various enantiopure or meso-type macrocyclic Schiff bases …

Recent advances in the synthesis and applications of nitrogen-containing macrocycles

J Grajewski - Molecules, 2022 - mdpi.com
Macrocyclic nitrogen-containing compounds are versatile molecules. Supramolecular,
noncovalent interactions of these macrocycles with guest molecules enables them to act as …

Effects of counterions, coordination anions, and coordination solvent molecules on single-molecule magnetic behaviors and nonlinear optical properties of chiral …

CM Liu, R Sun, BW Wang, X Hao, XL Li - Inorganic Chemistry, 2022 - ACS Publications
By changing the counterions (ClO4–and CF3SO3–) and the coordination anions (Cl–and Br–
), we investigated their influences on the structures and performances of a class of Zn2Dy …

Chiral Zn3Ln3 Hexanuclear Clusters of an Achiral Flexible Ligand

L Miao, MJ Liu, M Zeng, HZ Kou - Inorganic Chemistry, 2023 - ACS Publications
Multifunctional single-molecule magnets (SMMs) have sparked great interest, but chiral
SMMs obtained via spontaneous resolution are rarely reported. We synthesized a series of …

Anion-Manipulated Hydrolysis Process Assembles of Giant High-Nucleation Lanthanide-Oxo Cluster

HL Wang, YL Li, ZH Zhu, XL Lu, FP Liang… - Inorganic …, 2022 - ACS Publications
Widespread concern has been raised over the synthesis of highly nucleated lanthanide
clusters with special shapes and/or specific linkages. Construction of lanthanide clusters …

Preparation of chiral stationary phase based on a [3+ 3] chiral polyimine macrocycle by thiol-ene click chemistry for enantioseparation in normal-phase and reversed …

YP Zhang, LX Xiong, Y Wang, K Li, BJ Wang… - … of Chromatography A, 2022 - Elsevier
Polyimine macrocycles are a new class of organic macrocycles with cyclic structures, well-
defined molecular cavities, and multiple cooperative binding sites, which have recently …

A family of mono-, di-, and tetranuclear Dy III complexes bearing the ligand 2, 6-diacetylpyridine bis (picolinoylhydrazone) and exhibiting slow relaxation of …

AS Armenis, GP Bakali, CAL Brantley… - Dalton …, 2022 - pubs.rsc.org
The systematic investigation of the general reaction scheme DyIII/X−/LH2, where X−= Cl−,
CF3SO3−, ClO4−, MeCO2−, and LH2 is the pocket-type ligand 2, 6-diacetylpyridine bis …

Regulation of magnetic relaxation behavior by replacing 3d transition metal ions in [M 2 Dy 2] complexes containing two different organic chelating ligands

HS Wang, CL Yin, ZB Hu, Y Chen, ZQ Pan… - Dalton …, 2019 - pubs.rsc.org
Four tetranuclear 3d–4f complexes, namely [Fe2Ln2 (L) 2 (teaH) 2 (Cl) 2](NO3) 2· 4CH3CN
(H2L= N1, N3-bis (3-methoxysalicylidene) diethylenetriamine, teaH3= triethanolamine, Ln …

Solid state structures and solution behaviour of tetranuclear lanthanide (iii) carbonate-bridged coordination compounds of chiral 3+ 3 amine macrocycle

K Wydra, V Kinzhybalo, J Lisowski - Dalton Transactions, 2023 - pubs.rsc.org
The linking of two dinuclear macrocyclic units of large triphenolic hexaazamine by two
carbonate anions results in the formation of dimeric tetranuclear Sm (III), Eu (III) and Gd (III) …

Chiral Co-Crystals of (S)- or (R)-1,1′-Binaphthalene-2,2′-diol and Zn2Dy2 Tetranuclear Complexes Behaving as Single-Molecule Magnets

CM Liu, R Sun, X Hao, B Wang - Crystal Growth & Design, 2021 - ACS Publications
Co-crystals formed by coordination complex coformers and chiral organic coformers are
difficult to obtain. We found that chiral spiroborate anions (S, S)-and (R, R)-bis (1, 1 …