The use of carbon dioxide as an alternative feedstock for the production of polymeric
materials represents a promising strategy for the valorization of CO 2. In this regard, there …

Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and
net charges of transition states, products, and reactants to modify the free energy landscape …

Metalloenzymes with heteromultimetallic active sites perform chemical reactions that control
several biogeochemical cycles. Transformations catalyzed by such enzymes include …

Understanding the dynamic structural changes accompanying radical formation provides
detailed insights into the design of stimuli-responsive redox-active materials. In this study …

Alkali metals have low potentials and high capacities, making them ideal anodes for next‐
generation batteries, but they suffer major problems, including dendrite growth and low …

Redox-inactive metal-ion-driven modulation of the oxidation behavior of high-valent metal–
oxo complex has garnered significant interest in biological and chemical synthesis; …

A series heterodinuclear catalysts, operating without co‐catalyst, show good performances
for the ring opening copolymerization (ROCOP) of cyclohexene oxide and carbon dioxide …

Although crown ethers can selectively bind many metal cations, little is known regarding the
solution properties of crown ether complexes of the uranyl dication, UO22+. Here, the …

Gutmann–Beckett-type measurements with phosphine oxide probes can be used to estimate
effective Lewis acidity with 31P nuclear magnetic resonance spectroscopy, but the influence …

The 2, 2′-bipyridyl-6, 6′-dicarboxylate ligand (bdc) has been shown in prior work to
effectively capture the uranyl (VI) ion, UO22+, from aqueous solutions. However, the redox …