Chemistry of soft porous crystals: structural dynamics and gas adsorption properties

S Krause, N Hosono, S Kitagawa - … Chemie International Edition, 2020 - Wiley Online Library
In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by
characterizing their common structural features and the resulting structural softness and …

Reverse-selective metal–organic framework materials for the efficient separation and purification of light hydrocarbons

SQ Yang, TL Hu - Coordination Chemistry Reviews, 2022 - Elsevier
The separation and purification process of hydrocarbons is one of the crucial and daunting
challenges in the petrochemistry field, which is widely depended on cryogenic distillation by …

Directionally in situ self-assembled iridium (III)-polyimine complex-encapsulated metal–organic framework two-dimensional nanosheet electrode to boost …

H Qi, Z Wang, H Li, F Li - Analytical Chemistry, 2023 - ACS Publications
Manufacturing electrochemiluminescence (ECL) electrodes to detect analytes with high
performance in the aqueous phase for water-insoluble metal complexes is a great …

Four-dimensional metal-organic frameworks

JD Evans, V Bon, I Senkovska, HC Lee… - Nature …, 2020 - nature.com
Recognising timescale as an adjustable dimension in porous solids provides a new
perspective to develop novel four-dimensional framework materials. The deliberate design …

Design of hierarchical architectures in metal–oganic frameworks for catalysis and adsorption

FG Cirujano, N Martin, LH Wee - Chemistry of Materials, 2020 - ACS Publications
A key factor to improve the performance of metal–organic frameworks (MOFs) is the design
and synthesis of hierarchical interconnected porosity at different length scales. The …

Unraveling structure and dynamics in porous frameworks via advanced in situ characterization techniques

V Bon, E Brunner, A Pöppl… - Advanced Functional …, 2020 - Wiley Online Library
Dynamic metal–organic frameworks (MOFs) represent a subgroup of frameworks featuring
unique performance, as they are capable of adapting their pore size and/or the orientation of …

MOFs in the time domain

DJ Cerasale, DC Ward, TL Easun - Nature Reviews Chemistry, 2022 - nature.com
Many of the proposed applications of metal–organic framework (MOF) materials may fail to
materialize if the community does not fully address the difficult fundamental work needed to …

Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks

E Brunner, M Rauche - Chemical Science, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) gain increasing interest due to their outstanding
properties like extremely high porosity, structural variability, and various possibilities for …

Adaptive response of a metal–organic framework through reversible disorder–disorder transitions

S Ehrling, EM Reynolds, V Bon, I Senkovska… - Nature Chemistry, 2021 - nature.com
The ultrahigh porosity and varied functionalities of porous metal–organic frameworks make
them excellent candidates for applications that range widely from gas storage and …

Revolutionizing Porous Liquids: Stabilization and Structural Engineering Achieved by a Surface Deposition Strategy

L Qiu, H Peng, Z Yang, J Fan, M Li, S Yang… - Advanced …, 2023 - Wiley Online Library
Facile approaches capable of constructing stable and structurally diverse porous liquids
(PLs) that can deliver high‐performance applications are a long‐standing, captivating, and …