In the past decade, the asymmetric synthesis of chiral nonracemic isoquinoline alkaloids, a
family of natural products showing a wide range of structural diversity and biological and …

This review highlights a number of additives that can be used to make asymmetric reactions
perfect. Without changing other reaction conditions, simply adding additives can lead to …

The development of a mild and general method for C (sp3)− H functionalization of cyclic
amines has been an ongoing challenge. In this work, we describe the copper‐catalyzed …

Asymmetric A3 coupling has emerged as an important class of reactions to synthesise chiral
propargylamines. In this tutorial review, an up to date progress of this reaction, with …

Conspectus Redox-neutral methods for the functionalization of amine α-C–H bonds are
inherently efficient because they avoid external oxidants and reductants and often do not …

The first enantioselective alkynylation of benzylic C–H bonds via copper-catalyzed radical
relay has been established herein, which provides an easy access to structurally diverse …

Three-component dehydrogenative coupling reactions represent important and practical
methodologies for forging new C–N bonds and C–C bonds. Achieving highly all-in-one …

The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …

Axially chiral P, N-ligands have emerged as a powerful ligand class over time with
significant recent advances in terms of their synthesis, resolution, and applications to a …

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