Azulene, Reactivity, and Scientific Interest Inversely Proportional to Ring Size; Part 1: The Five-Membered Ring

AC Razus - Symmetry, 2023 - mdpi.com
The lack of azulene symmetry with respect to the axis perpendicular to a molecule creates
an asymmetry of the electronic system, increasing the charge density of the five-atom ring …

Electrochemistry of Rhodanine Derivatives as Model for New Colorimetric and Electrochemical Azulene Sensors for the Detection of Heavy Metal Ions

OT Matica, C Musina, AG Brotea, EM Ungureanu… - Symmetry, 2023 - mdpi.com
Rhodanine (R) is a heterocycle having complexing properties for heavy metal (HM) ions.
Considering the similar electron-donating character of diethylaminobenzene and azulene …

1-vinylazulenes with oxazolonic ring-potential ligands for metal ion detectors; synthesis and products properties

M Cristea, L Bîrzan, F Dumitrascu, C Enache… - Symmetry, 2021 - mdpi.com
As a continuation of research on 1-vinylazulenes synthesis, on their physico–chemical
properties as well as on their use as colorimetric and electrochemical materials for the …

[HTML][HTML] Polyazulene-Based Materials for Heavy Metal Ion Detection. 2. (E)-5-(azulen-1-yldiazenyl)-1H-Tetrazole-Modified Electrodes for Heavy Metal Sensing

LB Enache, V Anăstăsoaie, L Birzan, EM Ungureanu… - Coatings, 2020 - mdpi.com
Azulene-based materials present very appealing properties for the preparation of advanced
materials. They can be irreversibly electrooxidated, leading to polymers, which can be …

[HTML][HTML] Rapid and efficient uncatalyzed knoevenagel condensations from binary mixture of ethanol and water

JMGO Ferreira, J Resende Filho, PK Batista… - Journal of the Brazilian …, 2018 - SciELO Brasil
This paper presents a new green protocol for Knoevenagel condensations of aldehydes and
compounds with an active methylene group in a binary mixture of ethanol/water (3: 7, v/v) …

Electrochemical Comparison on New (Z)-5-(Azulen-1-Ylmethylene)-2-Thioxo-Thiazolidin-4-Ones

EM Ungureanu, M Popescu, GL Tatu, L Birzan… - Symmetry, 2021 - mdpi.com
Three (Z)-5-(azulen-1-ylmethylene)-2-thioxo-thiazolidin-4-ones are electrochemically
characterized by cyclic voltammetry, differential pulse voltammetry, and rotating disk …

[HTML][HTML] Sulfated polyborate as Bronsted acid catalyst for Knoevenagel condensation

P Ganwir, P Bandivadekar, G Chaturbhuj - Results in Chemistry, 2022 - Elsevier
We have developed the use of Bronsted acid for Knoevenagel condensation. Sulfated
polyborate has been used for efficient Knoevenagel condensation of aromatic, heterocyclic …

[PDF][PDF] New azulene modified electrodes for heavy metal ions recognition

GL Arnold, IG Lazar, GO Buica, EM Ungureanu… - Bulg. Chem …, 2017 - bcc.bas.bg
(E)-2-thioxo-5-((4, 6, 8-trimethylazulen-1-yl) methylene) thiazolidin-4-one (L) was
electrochemically characterized by cyclic voltammetry, differential pulse voltammetry and …

The synthesis and characterization of ylideneisoindolinones

BR Schrage, CA Farmer, VN Nemykin… - Journal of Porphyrins …, 2021 - World Scientific
1, 3-Diiminoisoindoline (DII) and the closely related molecule, iminoisoindolinone are
important precursors in the synthesis of macrocycles and chelates such as phthalocyanines …

[PDF][PDF] New azulene modified electrodes for heavy metal sensing

MD Pop, V Anastasoaie, MA Popescu, A Oprisanu… - Rev. Chim, 2017 - bch.ro
The electrochemical characterization of 2, 6-bis ((E)-2-(furan-2-yl) vinyl)-4-(5-isopropyl-3, 8-
dimethylazulen-1-yl) pyridine has been performed by cyclic voltammetry, differential pulse …